Efficient and selective epoxidation of styrene with TBHP catalyzed by Au25 clusters on hydroxyapatite

Yongmei Liu, Hironori Tsunoyama, Tomoki Akita, Tatsuya Tsukuda

Research output: Contribution to journalArticle

224 Citations (Scopus)

Abstract

Au25 clusters supported on hydroxyapatite oxidized styrene in toluene with 100% conversion and 92% selectivity to the epoxide, under optimum conditions and using anhydrous tert-butyl hydroperoxide (TBHP) as an oxidant.

Original languageEnglish
Pages (from-to)550-552
Number of pages3
JournalChemical Communications
Volume46
Issue number4
DOIs
Publication statusPublished - 2010
Externally publishedYes

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tert-Butylhydroperoxide
Styrene
Epoxidation
Epoxy Compounds
Toluene
Durapatite
Oxidants
Hydroxyapatite

ASJC Scopus subject areas

  • Metals and Alloys
  • Materials Chemistry
  • Surfaces, Coatings and Films
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Catalysis
  • Chemistry(all)

Cite this

Efficient and selective epoxidation of styrene with TBHP catalyzed by Au25 clusters on hydroxyapatite. / Liu, Yongmei; Tsunoyama, Hironori; Akita, Tomoki; Tsukuda, Tatsuya.

In: Chemical Communications, Vol. 46, No. 4, 2010, p. 550-552.

Research output: Contribution to journalArticle

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