Efficient and selective epoxidation of styrene with TBHP catalyzed by Au25 clusters on hydroxyapatite

Yongmei Liu; Hironori Tsunoyama; Tomoki Akita; Tatsuya Tsukuda

doi:10.1039/b921082b

Efficient and selective epoxidation of styrene with TBHP catalyzed by Au₂₅ clusters on hydroxyapatite

Yongmei Liu, Hironori Tsunoyama, Tomoki Akita, Tatsuya Tsukuda

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

269 Citations (Scopus)

Abstract

Au₂₅ clusters supported on hydroxyapatite oxidized styrene in toluene with 100% conversion and 92% selectivity to the epoxide, under optimum conditions and using anhydrous tert-butyl hydroperoxide (TBHP) as an oxidant.

Original language	English
Pages (from-to)	550-552
Number of pages	3
Journal	Chemical Communications
Volume	46
Issue number	4
DOIs	https://doi.org/10.1039/b921082b
Publication status	Published - 2010

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "Efficient and selective epoxidation of styrene with TBHP catalyzed by Au25 clusters on hydroxyapatite",

abstract = "Au25 clusters supported on hydroxyapatite oxidized styrene in toluene with 100% conversion and 92% selectivity to the epoxide, under optimum conditions and using anhydrous tert-butyl hydroperoxide (TBHP) as an oxidant.",

author = "Yongmei Liu and Hironori Tsunoyama and Tomoki Akita and Tatsuya Tsukuda",

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AU - Liu, Yongmei

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AU - Akita, Tomoki

AU - Tsukuda, Tatsuya

PY - 2010

Y1 - 2010

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AB - Au25 clusters supported on hydroxyapatite oxidized styrene in toluene with 100% conversion and 92% selectivity to the epoxide, under optimum conditions and using anhydrous tert-butyl hydroperoxide (TBHP) as an oxidant.

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U2 - 10.1039/b921082b

DO - 10.1039/b921082b

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JO - Chemical Communications

JF - Chemical Communications

IS - 4

ER -

Efficient and selective epoxidation of styrene with TBHP catalyzed by Au₂₅ clusters on hydroxyapatite

Abstract

ASJC Scopus subject areas

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