Efficient catalytic addition of aromatic carbon-hydrogen bonds to olefins

Shinji Murai; Fumitoshi Kakiuchi; Shinya Sekine; Yasuo Tanaka; Asayuki Kamatani; Motohiro Sonoda; Naoto Chatani

doi:10.1038/366529a0

Efficient catalytic addition of aromatic carbon-hydrogen bonds to olefins

Shinji Murai, Fumitoshi Kakiuchi, Shinya Sekine, Yasuo Tanaka, Asayuki Kamatani, Motohiro Sonoda, Naoto Chatani

Research output: Contribution to journal › Article › peer-review

1119 Citations (Scopus)

Abstract

The selective cleavage of carbon-hydrogen bonds in organic compounds is a critical step in many organic syntheses, and is particularly important in the conversion of hydrocarbons to useful organic compounds. An organometallic ruthenium complex can cleave C-H bonds in a variety of aromatic systems, leading to addition to alkenes by C-C bond formation. The catalyst operates with a degree of efficiency, selectivity and generality that will make it extremely valuable in organic synthesis.

Original language	English
Pages (from-to)	529-531
Number of pages	3
Journal	Nature
Volume	366
Issue number	6455
DOIs	https://doi.org/10.1038/366529a0
Publication status	Published - 1993
Externally published	Yes

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title = "Efficient catalytic addition of aromatic carbon-hydrogen bonds to olefins",

abstract = "The selective cleavage of carbon-hydrogen bonds in organic compounds is a critical step in many organic syntheses, and is particularly important in the conversion of hydrocarbons to useful organic compounds. An organometallic ruthenium complex can cleave C-H bonds in a variety of aromatic systems, leading to addition to alkenes by C-C bond formation. The catalyst operates with a degree of efficiency, selectivity and generality that will make it extremely valuable in organic synthesis.",

author = "Shinji Murai and Fumitoshi Kakiuchi and Shinya Sekine and Yasuo Tanaka and Asayuki Kamatani and Motohiro Sonoda and Naoto Chatani",

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AU - Murai, Shinji

AU - Kakiuchi, Fumitoshi

AU - Sekine, Shinya

AU - Tanaka, Yasuo

AU - Kamatani, Asayuki

AU - Sonoda, Motohiro

AU - Chatani, Naoto

PY - 1993

Y1 - 1993

N2 - The selective cleavage of carbon-hydrogen bonds in organic compounds is a critical step in many organic syntheses, and is particularly important in the conversion of hydrocarbons to useful organic compounds. An organometallic ruthenium complex can cleave C-H bonds in a variety of aromatic systems, leading to addition to alkenes by C-C bond formation. The catalyst operates with a degree of efficiency, selectivity and generality that will make it extremely valuable in organic synthesis.

AB - The selective cleavage of carbon-hydrogen bonds in organic compounds is a critical step in many organic syntheses, and is particularly important in the conversion of hydrocarbons to useful organic compounds. An organometallic ruthenium complex can cleave C-H bonds in a variety of aromatic systems, leading to addition to alkenes by C-C bond formation. The catalyst operates with a degree of efficiency, selectivity and generality that will make it extremely valuable in organic synthesis.

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Efficient catalytic addition of aromatic carbon-hydrogen bonds to olefins

Abstract

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