Efficient catalytic addition of aromatic carbon-hydrogen bonds to olefins

Shinji Murai; Fumitoshi Kakiuchi; Shinya Sekine; Yasuo Tanaka; Asayuki Kamatani; Motohiro Sonoda; Naoto Chatani

doi:10.1038/366529a0

Efficient catalytic addition of aromatic carbon-hydrogen bonds to olefins

Shinji Murai, Fumitoshi Kakiuchi, Shinya Sekine, Yasuo Tanaka, Asayuki Kamatani, Motohiro Sonoda, Naoto Chatani

Department of Chemistry

Research output: Contribution to journal › Article

1035 Citations (Scopus)

Abstract

The selective cleavage of carbon-hydrogen bonds in organic compounds is a critical step in many organic syntheses, and is particularly important in the conversion of hydrocarbons to useful organic compounds. An organometallic ruthenium complex can cleave C-H bonds in a variety of aromatic systems, leading to addition to alkenes by C-C bond formation. The catalyst operates with a degree of efficiency, selectivity and generality that will make it extremely valuable in organic synthesis.

Original language	English
Pages (from-to)	529-531
Number of pages	3
Journal	Nature
Volume	366
Issue number	6455
DOIs	https://doi.org/10.1038/366529a0
Publication status	Published - 1993

ASJC Scopus subject areas

General

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Murai, S., Kakiuchi, F., Sekine, S., Tanaka, Y., Kamatani, A., Sonoda, M., & Chatani, N. (1993). Efficient catalytic addition of aromatic carbon-hydrogen bonds to olefins. Nature, 366(6455), 529-531. https://doi.org/10.1038/366529a0

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AU - Kamatani, Asayuki

AU - Sonoda, Motohiro

AU - Chatani, Naoto

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