Efficient preparation of C2-symmetrical chiral ferrocenyl diols by catalytic enantioselective reduction of diacylferrocenes

Hirohide Sato, Hiroto Watanabe, Yuhki Ohtsuka, Taketo Ikeno, Shin Ichi Fukuzawa, Tohru Yamada

Research output: Contribution to journalArticle

26 Citations (Scopus)

Abstract

equation presented Enantioselective borohydride reduction, catalyzed by the optically active β-ketoiminato cobalt(III) complex, was successfully applied to the 1,1′-dialkanoyl- and 1,1′-dibenzoylferrocenes to afford the corresponding C2-symmetrical chiral ferrocenyl diols with high diastereoselectivity and excellent enantioselectivity.

Original languageEnglish
Pages (from-to)3313-3316
Number of pages4
JournalOrganic Letters
Volume4
Issue number19
DOIs
Publication statusPublished - 2002 Sep 19

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Borohydrides
borohydrides
Enantioselectivity
Cobalt
cobalt
preparation

ASJC Scopus subject areas

  • Molecular Medicine

Cite this

Efficient preparation of C2-symmetrical chiral ferrocenyl diols by catalytic enantioselective reduction of diacylferrocenes. / Sato, Hirohide; Watanabe, Hiroto; Ohtsuka, Yuhki; Ikeno, Taketo; Fukuzawa, Shin Ichi; Yamada, Tohru.

In: Organic Letters, Vol. 4, No. 19, 19.09.2002, p. 3313-3316.

Research output: Contribution to journalArticle

Sato, Hirohide ; Watanabe, Hiroto ; Ohtsuka, Yuhki ; Ikeno, Taketo ; Fukuzawa, Shin Ichi ; Yamada, Tohru. / Efficient preparation of C2-symmetrical chiral ferrocenyl diols by catalytic enantioselective reduction of diacylferrocenes. In: Organic Letters. 2002 ; Vol. 4, No. 19. pp. 3313-3316.
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AU - Fukuzawa, Shin Ichi

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