Efficient preparation of C2-symmetrical chiral ferrocenyl diols by catalytic enantioselective reduction of diacylferrocenes

Hirohide Sato; Hiroto Watanabe; Yuhki Ohtsuka; Taketo Ikeno; Shin Ichi Fukuzawa; Tohru Yamada

doi:10.1021/ol0266018

Efficient preparation of C₂-symmetrical chiral ferrocenyl diols by catalytic enantioselective reduction of diacylferrocenes

Hirohide Sato, Hiroto Watanabe, Yuhki Ohtsuka, Taketo Ikeno, Shin Ichi Fukuzawa, Tohru Yamada

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

27 Citations (Scopus)

Abstract

equation presented Enantioselective borohydride reduction, catalyzed by the optically active β-ketoiminato cobalt(III) complex, was successfully applied to the 1,1′-dialkanoyl- and 1,1′-dibenzoylferrocenes to afford the corresponding C₂-symmetrical chiral ferrocenyl diols with high diastereoselectivity and excellent enantioselectivity.

Original language	English
Pages (from-to)	3313-3316
Number of pages	4
Journal	Organic Letters
Volume	4
Issue number	19
DOIs	https://doi.org/10.1021/ol0266018
Publication status	Published - 2002 Sep 19

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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title = "Efficient preparation of C2-symmetrical chiral ferrocenyl diols by catalytic enantioselective reduction of diacylferrocenes",

abstract = "equation presented Enantioselective borohydride reduction, catalyzed by the optically active β-ketoiminato cobalt(III) complex, was successfully applied to the 1,1′-dialkanoyl- and 1,1′-dibenzoylferrocenes to afford the corresponding C2-symmetrical chiral ferrocenyl diols with high diastereoselectivity and excellent enantioselectivity.",

author = "Hirohide Sato and Hiroto Watanabe and Yuhki Ohtsuka and Taketo Ikeno and Fukuzawa, {Shin Ichi} and Tohru Yamada",

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T1 - Efficient preparation of C2-symmetrical chiral ferrocenyl diols by catalytic enantioselective reduction of diacylferrocenes

AU - Sato, Hirohide

AU - Watanabe, Hiroto

AU - Ohtsuka, Yuhki

AU - Ikeno, Taketo

AU - Fukuzawa, Shin Ichi

AU - Yamada, Tohru

PY - 2002/9/19

Y1 - 2002/9/19

N2 - equation presented Enantioselective borohydride reduction, catalyzed by the optically active β-ketoiminato cobalt(III) complex, was successfully applied to the 1,1′-dialkanoyl- and 1,1′-dibenzoylferrocenes to afford the corresponding C2-symmetrical chiral ferrocenyl diols with high diastereoselectivity and excellent enantioselectivity.

AB - equation presented Enantioselective borohydride reduction, catalyzed by the optically active β-ketoiminato cobalt(III) complex, was successfully applied to the 1,1′-dialkanoyl- and 1,1′-dibenzoylferrocenes to afford the corresponding C2-symmetrical chiral ferrocenyl diols with high diastereoselectivity and excellent enantioselectivity.

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