Efficient preparation of optically pure C2-symmetrical cyclic amines for chiral auxiliary

Mitsuo Sato; Yasuhiko Gunji; Taketo Ikeno; Tohru Yamada

doi:10.1055/s-2004-822366

Efficient preparation of optically pure C₂-symmetrical cyclic amines for chiral auxiliary

Mitsuo Sato, Yasuhiko Gunji, Taketo Ikeno, Tohru Yamada

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

30 Citations (Scopus)

Abstract

Optically pure C₂-symmetrical amines were efficiently synthesized from the corresponding diols obtained from the enantioselective borohydride reduction of the diketones catalyzed by the optically active β-ketoiminato cobalt(II) complex.

Original language	English
Pages (from-to)	1434-1438
Number of pages	5
Journal	Synthesis
Issue number	9
DOIs	https://doi.org/10.1055/s-2004-822366
Publication status	Published - 2004 Jun 18

Keywords

Asymmetric reduction
Borohydride
Chiral diols
Cobalt
Cyclic chiral amines

ASJC Scopus subject areas

Catalysis
Organic Chemistry

Access to Document

10.1055/s-2004-822366

Cite this

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title = "Efficient preparation of optically pure C2-symmetrical cyclic amines for chiral auxiliary",

abstract = "Optically pure C2-symmetrical amines were efficiently synthesized from the corresponding diols obtained from the enantioselective borohydride reduction of the diketones catalyzed by the optically active β-ketoiminato cobalt(II) complex.",

keywords = "Asymmetric reduction, Borohydride, Chiral diols, Cobalt, Cyclic chiral amines",

author = "Mitsuo Sato and Yasuhiko Gunji and Taketo Ikeno and Tohru Yamada",

year = "2004",

month = jun,

day = "18",

doi = "10.1055/s-2004-822366",

language = "English",

pages = "1434--1438",

journal = "Synthesis (Germany)",

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publisher = "Georg Thieme Verlag",

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T1 - Efficient preparation of optically pure C2-symmetrical cyclic amines for chiral auxiliary

AU - Sato, Mitsuo

AU - Gunji, Yasuhiko

AU - Ikeno, Taketo

AU - Yamada, Tohru

PY - 2004/6/18

Y1 - 2004/6/18

N2 - Optically pure C2-symmetrical amines were efficiently synthesized from the corresponding diols obtained from the enantioselective borohydride reduction of the diketones catalyzed by the optically active β-ketoiminato cobalt(II) complex.

AB - Optically pure C2-symmetrical amines were efficiently synthesized from the corresponding diols obtained from the enantioselective borohydride reduction of the diketones catalyzed by the optically active β-ketoiminato cobalt(II) complex.

KW - Asymmetric reduction

KW - Borohydride

KW - Chiral diols

KW - Cobalt

KW - Cyclic chiral amines

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