Efficient preparation of optically pure C2-symmetrical cyclic amines for chiral auxiliary

Mitsuo Sato, Yasuhiko Gunji, Taketo Ikeno, Tohru Yamada

Research output: Contribution to journalArticle

26 Citations (Scopus)

Abstract

Optically pure C2-symmetrical amines were efficiently synthesized from the corresponding diols obtained from the enantioselective borohydride reduction of the diketones catalyzed by the optically active β-ketoiminato cobalt(II) complex.

Original languageEnglish
Pages (from-to)1434-1438
Number of pages5
JournalSynthesis
Issue number9
Publication statusPublished - 2004 Jun 18

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Borohydrides
Cobalt
Amines

Keywords

  • Asymmetric reduction
  • Borohydride
  • Chiral diols
  • Cobalt
  • Cyclic chiral amines

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

Efficient preparation of optically pure C2-symmetrical cyclic amines for chiral auxiliary. / Sato, Mitsuo; Gunji, Yasuhiko; Ikeno, Taketo; Yamada, Tohru.

In: Synthesis, No. 9, 18.06.2004, p. 1434-1438.

Research output: Contribution to journalArticle

Sato, Mitsuo ; Gunji, Yasuhiko ; Ikeno, Taketo ; Yamada, Tohru. / Efficient preparation of optically pure C2-symmetrical cyclic amines for chiral auxiliary. In: Synthesis. 2004 ; No. 9. pp. 1434-1438.
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