Electrical conductivity modulation coupled to a high-spin-low-spin conversion in the molecular system [FeIII(qsal)2][Ni(dmit) 2]3·CH3CN·H2O

Kazuyuki Takahashi, Heng Bo Cui, Yoshinori Okano, Hayao Kobayashi, Yasuaki Einaga, Osamu Sato

Research output: Contribution to journalArticle

102 Citations (Scopus)

Abstract

The synergy between the electrical conductivity within the stacks of Ni(dmit)2 in the newly electrocrystallized [Fe(qsal) 2][Ni(dmit)2]3· CH3CN· H2O and the spin conversion of Fe(qsal)2 is evidenced. In addition, the presence of a light-induced excited spin state trapping effect suggests that this complex is a prototypal photoswitchable spin-crossover molecular conductor.

Original languageEnglish
Pages (from-to)5739-5741
Number of pages3
JournalInorganic Chemistry
Volume45
Issue number15
DOIs
Publication statusPublished - 2006 Jul 24

Fingerprint

Modulation
modulation
electrical resistivity
crossovers
conductors
trapping
Electric Conductivity

ASJC Scopus subject areas

  • Inorganic Chemistry

Cite this

Electrical conductivity modulation coupled to a high-spin-low-spin conversion in the molecular system [FeIII(qsal)2][Ni(dmit) 2]3·CH3CN·H2O. / Takahashi, Kazuyuki; Cui, Heng Bo; Okano, Yoshinori; Kobayashi, Hayao; Einaga, Yasuaki; Sato, Osamu.

In: Inorganic Chemistry, Vol. 45, No. 15, 24.07.2006, p. 5739-5741.

Research output: Contribution to journalArticle

Takahashi, Kazuyuki ; Cui, Heng Bo ; Okano, Yoshinori ; Kobayashi, Hayao ; Einaga, Yasuaki ; Sato, Osamu. / Electrical conductivity modulation coupled to a high-spin-low-spin conversion in the molecular system [FeIII(qsal)2][Ni(dmit) 2]3·CH3CN·H2O. In: Inorganic Chemistry. 2006 ; Vol. 45, No. 15. pp. 5739-5741.
@article{ba7e4072db3b4900b940ed699d77a56d,
title = "Electrical conductivity modulation coupled to a high-spin-low-spin conversion in the molecular system [FeIII(qsal)2][Ni(dmit) 2]3·CH3CN·H2O",
abstract = "The synergy between the electrical conductivity within the stacks of Ni(dmit)2 in the newly electrocrystallized [Fe(qsal) 2][Ni(dmit)2]3· CH3CN· H2O and the spin conversion of Fe(qsal)2 is evidenced. In addition, the presence of a light-induced excited spin state trapping effect suggests that this complex is a prototypal photoswitchable spin-crossover molecular conductor.",
author = "Kazuyuki Takahashi and Cui, {Heng Bo} and Yoshinori Okano and Hayao Kobayashi and Yasuaki Einaga and Osamu Sato",
year = "2006",
month = "7",
day = "24",
doi = "10.1021/ic060852l",
language = "English",
volume = "45",
pages = "5739--5741",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",
number = "15",

}

TY - JOUR

T1 - Electrical conductivity modulation coupled to a high-spin-low-spin conversion in the molecular system [FeIII(qsal)2][Ni(dmit) 2]3·CH3CN·H2O

AU - Takahashi, Kazuyuki

AU - Cui, Heng Bo

AU - Okano, Yoshinori

AU - Kobayashi, Hayao

AU - Einaga, Yasuaki

AU - Sato, Osamu

PY - 2006/7/24

Y1 - 2006/7/24

N2 - The synergy between the electrical conductivity within the stacks of Ni(dmit)2 in the newly electrocrystallized [Fe(qsal) 2][Ni(dmit)2]3· CH3CN· H2O and the spin conversion of Fe(qsal)2 is evidenced. In addition, the presence of a light-induced excited spin state trapping effect suggests that this complex is a prototypal photoswitchable spin-crossover molecular conductor.

AB - The synergy between the electrical conductivity within the stacks of Ni(dmit)2 in the newly electrocrystallized [Fe(qsal) 2][Ni(dmit)2]3· CH3CN· H2O and the spin conversion of Fe(qsal)2 is evidenced. In addition, the presence of a light-induced excited spin state trapping effect suggests that this complex is a prototypal photoswitchable spin-crossover molecular conductor.

UR - http://www.scopus.com/inward/record.url?scp=33746916065&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=33746916065&partnerID=8YFLogxK

U2 - 10.1021/ic060852l

DO - 10.1021/ic060852l

M3 - Article

VL - 45

SP - 5739

EP - 5741

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

IS - 15

ER -