Electrical conductivity modulation coupled to a high-spin-low-spin conversion in the molecular system [FeIII(qsal)2][Ni(dmit) 2]3·CH3CN·H2O

Kazuyuki Takahashi, Heng Bo Cui, Yoshinori Okano, Hayao Kobayashi, Yasuaki Einaga, Osamu Sato

Research output: Contribution to journalArticle

105 Citations (Scopus)

Abstract

The synergy between the electrical conductivity within the stacks of Ni(dmit)2 in the newly electrocrystallized [Fe(qsal) 2][Ni(dmit)2]3· CH3CN· H2O and the spin conversion of Fe(qsal)2 is evidenced. In addition, the presence of a light-induced excited spin state trapping effect suggests that this complex is a prototypal photoswitchable spin-crossover molecular conductor.

Original languageEnglish
Pages (from-to)5739-5741
Number of pages3
JournalInorganic Chemistry
Volume45
Issue number15
DOIs
Publication statusPublished - 2006 Jul 24

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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