Electrochemical behavior of bis(acetylacetonato)platinum(II) complex in an amide-type ionic liquid

Sharmin Sultana, Naoki Tachikawa, Kazuki Yoshii, Luca Magagnin, Kazunobu Toshima, Yasushi Katayama

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

Electrochemical behavior of bis(acetylacetonato)platinum(II) (Pt(acac)2) was investigated in an amide-type ionic liquid, trimethylhexylammonium bis(trifluoromethylsulfonyl)amide(TMHATFSA), at various temperatures. Ultraviolet visible spectroscopy revealed the existence of Pt(acac)2 having square planar geometry in TMHATFSA. The electrochemical reduction of Pt(acac)2 to Pt(0) was considered to occur with formation of some intermediate species of Pt by cyclic voltammetry. Potentiostatic cathodic reduction on a glassy carbon electrode in TMHATFSA containing Pt(acac)2 at -1.7 V at 130°C resulted in deposition of metallic Pt, which was confirmed by scanning electron microscopy and energy dispersive X-ray spectroscopy. In addition, formation of Pt nanoparticles dispersed in the ionic liquid after potentiostatic cathodic reduction was confirmed by transmission electron microscopy and electron diffraction. The sizes of the Pt nanoparticles were found to depend on the reduction potential.

Original languageEnglish
Pages (from-to)D401-D406
JournalJournal of the Electrochemical Society
Volume163
Issue number8
DOIs
Publication statusPublished - 2016

Fingerprint

Ionic Liquids
Platinum
Amides
Ionic liquids
amides
platinum
liquids
Nanoparticles
nanoparticles
glassy carbon
Ultraviolet visible spectroscopy
Glassy carbon
Electron diffraction
spectroscopy
Cyclic voltammetry
electron diffraction
electron energy
Transmission electron microscopy
transmission electron microscopy
Scanning electron microscopy

ASJC Scopus subject areas

  • Electrochemistry
  • Electronic, Optical and Magnetic Materials
  • Materials Chemistry
  • Surfaces, Coatings and Films
  • Renewable Energy, Sustainability and the Environment
  • Condensed Matter Physics

Cite this

Electrochemical behavior of bis(acetylacetonato)platinum(II) complex in an amide-type ionic liquid. / Sultana, Sharmin; Tachikawa, Naoki; Yoshii, Kazuki; Magagnin, Luca; Toshima, Kazunobu; Katayama, Yasushi.

In: Journal of the Electrochemical Society, Vol. 163, No. 8, 2016, p. D401-D406.

Research output: Contribution to journalArticle

Sultana, Sharmin ; Tachikawa, Naoki ; Yoshii, Kazuki ; Magagnin, Luca ; Toshima, Kazunobu ; Katayama, Yasushi. / Electrochemical behavior of bis(acetylacetonato)platinum(II) complex in an amide-type ionic liquid. In: Journal of the Electrochemical Society. 2016 ; Vol. 163, No. 8. pp. D401-D406.
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