Electrochemical behavior of oxygen / superoxide ion couple in 1-butyl-1-methylpyrrolidinium bis(trifluoromethanesulfone)imide room-temperature molten salt

Yasushi Katayama; Kaori Sekiguchi; Masaki Yamagata; Takashi Miura

Electrochemical behavior of oxygen / superoxide ion couple in 1-butyl-1-methylpyrrolidinium bis(trifluoromethanesulfone)imide room-temperature molten salt

Yasushi Katayama, Kaori Sekiguchi, Masaki Yamagata, Takashi Miura

Department of Applied Chemistry

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

2 Citations (Scopus)

Abstract

The electrochemical behavior of oxygen (O₂) superoxide ion (O₂) couple was investigated with the aid of ultra micro electrode technique in 1-butyl-1-methylpyrrolidinium bis(trifluoromethanesulfone)imide room-temperature molten salt. The diffusion coefficient of O₂ was (1.8 ± 0.2) × 10^-6 cm² s^-1 at 25°C. The activation energy of the diffusion process of O₂ was estimated to be 27 kJ mol^-1 from the temperature dependence of the diffusion coefficient. The solubility of O₂ in BMPTFSI was 14 mmol dm^-3 at 25°C and decreased with an increase in temperature. The diffusion coefficient of O₂^- was 0.86 × 10 ^-6 cm² s^-1 at 25°C. The formal potential of O₂ O₂^- couple was 1.13 V vs. ferrocene / ferrocenium.

Original language	English
Title of host publication	Molten Salts XIV - Proceedings of the International Symposium
Pages	503-512
Number of pages	10
Publication status	Published - 2006 Dec 1
Event	206th ECS Meeting - Honolulu, HI, United States Duration: 2004 Oct 3 → 2004 Oct 8

Publication series

Name	Proceedings - Electrochemical Society
Volume	PV 2004-24

Other

Other	206th ECS Meeting
Country/Territory	United States
City	Honolulu, HI
Period	04/10/3 → 04/10/8

ASJC Scopus subject areas

Engineering(all)

Cite this

Electrochemical behavior of oxygen / superoxide ion couple in 1-butyl-1-methylpyrrolidinium bis(trifluoromethanesulfone)imide room-temperature molten salt. / Katayama, Yasushi; Sekiguchi, Kaori; Yamagata, Masaki et al.

Molten Salts XIV - Proceedings of the International Symposium. 2006. p. 503-512 (Proceedings - Electrochemical Society; Vol. PV 2004-24).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Katayama, Y, Sekiguchi, K, Yamagata, M & Miura, T 2006, Electrochemical behavior of oxygen / superoxide ion couple in 1-butyl-1-methylpyrrolidinium bis(trifluoromethanesulfone)imide room-temperature molten salt. in Molten Salts XIV - Proceedings of the International Symposium. Proceedings - Electrochemical Society, vol. PV 2004-24, pp. 503-512, 206th ECS Meeting, Honolulu, HI, United States, 04/10/3.

@inproceedings{aa179e6330ef411a89e66959074d41d8,

title = "Electrochemical behavior of oxygen / superoxide ion couple in 1-butyl-1-methylpyrrolidinium bis(trifluoromethanesulfone)imide room-temperature molten salt",

abstract = "The electrochemical behavior of oxygen (O2) superoxide ion (O2) couple was investigated with the aid of ultra micro electrode technique in 1-butyl-1-methylpyrrolidinium bis(trifluoromethanesulfone)imide room-temperature molten salt. The diffusion coefficient of O2 was (1.8 ± 0.2) × 10-6 cm2 s-1 at 25°C. The activation energy of the diffusion process of O2 was estimated to be 27 kJ mol-1 from the temperature dependence of the diffusion coefficient. The solubility of O2 in BMPTFSI was 14 mmol dm-3 at 25°C and decreased with an increase in temperature. The diffusion coefficient of O2- was 0.86 × 10 -6 cm2 s-1 at 25°C. The formal potential of O2 O2- couple was 1.13 V vs. ferrocene / ferrocenium.",

author = "Yasushi Katayama and Kaori Sekiguchi and Masaki Yamagata and Takashi Miura",

year = "2006",

month = dec,

day = "1",

language = "English",

isbn = "9781566775144",

series = "Proceedings - Electrochemical Society",

pages = "503--512",

booktitle = "Molten Salts XIV - Proceedings of the International Symposium",

note = "206th ECS Meeting ; Conference date: 03-10-2004 Through 08-10-2004",

}

TY - GEN

T1 - Electrochemical behavior of oxygen / superoxide ion couple in 1-butyl-1-methylpyrrolidinium bis(trifluoromethanesulfone)imide room-temperature molten salt

AU - Katayama, Yasushi

AU - Sekiguchi, Kaori

AU - Yamagata, Masaki

AU - Miura, Takashi

PY - 2006/12/1

Y1 - 2006/12/1

N2 - The electrochemical behavior of oxygen (O2) superoxide ion (O2) couple was investigated with the aid of ultra micro electrode technique in 1-butyl-1-methylpyrrolidinium bis(trifluoromethanesulfone)imide room-temperature molten salt. The diffusion coefficient of O2 was (1.8 ± 0.2) × 10-6 cm2 s-1 at 25°C. The activation energy of the diffusion process of O2 was estimated to be 27 kJ mol-1 from the temperature dependence of the diffusion coefficient. The solubility of O2 in BMPTFSI was 14 mmol dm-3 at 25°C and decreased with an increase in temperature. The diffusion coefficient of O2- was 0.86 × 10 -6 cm2 s-1 at 25°C. The formal potential of O2 O2- couple was 1.13 V vs. ferrocene / ferrocenium.

AB - The electrochemical behavior of oxygen (O2) superoxide ion (O2) couple was investigated with the aid of ultra micro electrode technique in 1-butyl-1-methylpyrrolidinium bis(trifluoromethanesulfone)imide room-temperature molten salt. The diffusion coefficient of O2 was (1.8 ± 0.2) × 10-6 cm2 s-1 at 25°C. The activation energy of the diffusion process of O2 was estimated to be 27 kJ mol-1 from the temperature dependence of the diffusion coefficient. The solubility of O2 in BMPTFSI was 14 mmol dm-3 at 25°C and decreased with an increase in temperature. The diffusion coefficient of O2- was 0.86 × 10 -6 cm2 s-1 at 25°C. The formal potential of O2 O2- couple was 1.13 V vs. ferrocene / ferrocenium.

UR - http://www.scopus.com/inward/record.url?scp=40249118996&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=40249118996&partnerID=8YFLogxK

M3 - Conference contribution

AN - SCOPUS:40249118996

SN - 9781566775144

T3 - Proceedings - Electrochemical Society

SP - 503

EP - 512

BT - Molten Salts XIV - Proceedings of the International Symposium

T2 - 206th ECS Meeting

Y2 - 3 October 2004 through 8 October 2004

ER -

Electrochemical behavior of oxygen / superoxide ion couple in 1-butyl-1-methylpyrrolidinium bis(trifluoromethanesulfone)imide room-temperature molten salt

Abstract

Publication series

Other

ASJC Scopus subject areas

Other files and links

Fingerprint

Cite this