@inproceedings{476d4fabdbbc41ae86b56b6437fe862a,
title = "Electrochemical behavior of silver halogenocomplexes in an amide-type ionic liquid",
abstract = "The electrochemical behavior of halogenocomplexes of Ag was investigated in an amide-type ionic liquid, 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)amide (BMPTFSA) in the presence of the corresponding halogen anion. Silver halides, AgX (X- = Cl-, Br-, and I-) were found to be soluble in BMPTFSA containing 0.5 M BMPX by forming [AgX3]2-. The cathodic reduction of [AgX3]2- to metallic Ag was possible within the electrochemical window of BMPTFSA. The reduction potentials were in the order of [AgCl3]2- > [AgBr3]2- > [AgI3]2-. The morphology of Ag deposits depended on the reduction potential. The diffusion coefficients of [AgCl3]2-, [AgBr3]2-, and [AgI3]2- were 2.5, 2.0, and 1.6 × 10-7 cm2 s-1, respectively. Formation of Ag nanoparticles dispersed in the ionic liquids was confirmed after potentiostatic cathodic reduction at -2.5 V using transmission electron microscopy.",
author = "Nobuyuki Serizawa and Suguru Kuwahara and Yasushi Katayama",
note = "Funding Information: Part of this study was supported by the Impulsing Paradigm Change through Disruptive Technologies Program (ImPACT) from Cabinet Office, Government of Japan. Publisher Copyright: {\textcopyright} The Electrochemical Society; Pacific Rim Meeting on Electrochemical and Solid State Science 2020, PRiME 200 ; Conference date: 04-10-2020 Through 09-10-2020",
year = "2020",
doi = "10.1149/09810.0209ecst",
language = "English",
series = "ECS Transactions",
publisher = "IOP Publishing Ltd.",
number = "10",
pages = "209--214",
editor = "Durkin, {D. P.} and Trulove, {P. C.} and A. Bund and A. Ispas and {Di Noto}, V. and Reichert, {W. M.} and Mantz, {R. A.} and {De Long}, {H. C.} and M. Mizuhata and M. Ueda",
booktitle = "PRiME 2020",
address = "United Kingdom",
edition = "10",
}