Abstract
The electrode reaction of tris(2,2'-bipyridine)cobalt complex, [Co(bpy)3]3+/2+, has been investigated in 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)amide (BMPTFSA) and 1-ethyl-3-methylimidazolium tetrafluoroborate (EMIBF4). Diffusion of [Co(bpy)3]2+ and [Co(bpy)3]3+ was affected by the viscosity and the charge densities of the complex and the anion of ionic liquid. The large change of the electron configurations of [Co(bpy)3]2+ and [Co(bpy)3]3+ is considered to cause the slow charge transfer and large reaction entropy change.
Original language | English |
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Title of host publication | Molten Salts and Ionic Liquids 20 |
Publisher | Electrochemical Society Inc. |
Pages | 497-505 |
Number of pages | 9 |
Volume | 75 |
Edition | 15 |
ISBN (Electronic) | 9781607685395 |
DOIs | |
Publication status | Published - 2016 |
Event | Symposium on Molten Salts and Ionic Liquids 20 - PRiME 2016/230th ECS Meeting - Honolulu, United States Duration: 2016 Oct 2 → 2016 Oct 7 |
Other
Other | Symposium on Molten Salts and Ionic Liquids 20 - PRiME 2016/230th ECS Meeting |
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Country | United States |
City | Honolulu |
Period | 16/10/2 → 16/10/7 |
ASJC Scopus subject areas
- Engineering(all)