Electrochemical Behavior of Vanadium Trichloride in 1-ethyl-3-methyimidazolium Chloride-Aluminum Trichloride Molten Salt

Yasushi Katayama, Isamu Konishiike, Takashi Miura, Tomiya Kishi

Research output: Contribution to journal › Article

3 Citations (Scopus)

Abstract

Electrochemical behavior of trivalent vanadium species was investigated in a Lewis basic 1-ethyl-3-methylimidazolium chloride (EMIC)-aluminum trichloride (AlCl3) molten salt at room temperature. The reduction of V(III) was observed around -1.2 V vs. Al(III) / Al in the cyclic voltammogram on platinum electrode. The reduction process of V(III) seems electrochemically irreversible as observed in aqueous solution.

Original languageEnglish
Pages (from-to)547-549
Number of pages3
JournalElectrochemistry
Volume67
Issue number6
Publication statusPublished - 1999

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Aluminum chloride
Vanadium
Molten materials
Salts
Platinum
Electrodes
Temperature
aluminum chloride
1-ethyl-3-methylimidazolium

Keywords

  • 1-ethyl-3-methylimidazolium chloride-aluminum trichloride
  • Vanadium trichloride

ASJC Scopus subject areas

  • Electrochemistry

Cite this

Electrochemical Behavior of Vanadium Trichloride in 1-ethyl-3-methyimidazolium Chloride-Aluminum Trichloride Molten Salt. / Katayama, Yasushi; Konishiike, Isamu; Miura, Takashi; Kishi, Tomiya.

In: Electrochemistry, Vol. 67, No. 6, 1999, p. 547-549.

Research output: Contribution to journal › Article

Katayama, Y, Konishiike, I, Miura, T & Kishi, T 1999, 'Electrochemical Behavior of Vanadium Trichloride in 1-ethyl-3-methyimidazolium Chloride-Aluminum Trichloride Molten Salt', Electrochemistry, vol. 67, no. 6, pp. 547-549.
Katayama Y, Konishiike I, Miura T, Kishi T. Electrochemical Behavior of Vanadium Trichloride in 1-ethyl-3-methyimidazolium Chloride-Aluminum Trichloride Molten Salt. Electrochemistry. 1999;67(6):547-549.
Katayama, Yasushi ; Konishiike, Isamu ; Miura, Takashi ; Kishi, Tomiya. / Electrochemical Behavior of Vanadium Trichloride in 1-ethyl-3-methyimidazolium Chloride-Aluminum Trichloride Molten Salt. In: Electrochemistry. 1999 ; Vol. 67, No. 6. pp. 547-549.
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