Abstract
Electrochemical behavior of trivalent vanadium species was investigated in a Lewis basic 1-ethyl-3-methylimidazolium chloride (EMIC)-aluminum trichloride (AlCl3) molten salt at room temperature. The reduction of V(III) was observed around -1.2 V vs. Al(III) / Al in the cyclic voltammogram on platinum electrode. The reduction process of V(III) seems electrochemically irreversible as observed in aqueous solution.
| Original language | English |
|---|---|
| Pages (from-to) | 547-549 |
| Number of pages | 3 |
| Journal | Electrochemistry |
| Volume | 67 |
| Issue number | 6 |
| Publication status | Published - 1999 |
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Keywords
- 1-ethyl-3-methylimidazolium chloride-aluminum trichloride
- Vanadium trichloride
ASJC Scopus subject areas
- Electrochemistry
Cite this
Electrochemical Behavior of Vanadium Trichloride in 1-ethyl-3-methyimidazolium Chloride-Aluminum Trichloride Molten Salt. / Katayama, Yasushi; Konishiike, Isamu; Miura, Takashi; Kishi, Tomiya.
In: Electrochemistry, Vol. 67, No. 6, 1999, p. 547-549.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Electrochemical Behavior of Vanadium Trichloride in 1-ethyl-3-methyimidazolium Chloride-Aluminum Trichloride Molten Salt
AU - Katayama, Yasushi
AU - Konishiike, Isamu
AU - Miura, Takashi
AU - Kishi, Tomiya
PY - 1999
Y1 - 1999
N2 - Electrochemical behavior of trivalent vanadium species was investigated in a Lewis basic 1-ethyl-3-methylimidazolium chloride (EMIC)-aluminum trichloride (AlCl3) molten salt at room temperature. The reduction of V(III) was observed around -1.2 V vs. Al(III) / Al in the cyclic voltammogram on platinum electrode. The reduction process of V(III) seems electrochemically irreversible as observed in aqueous solution.
AB - Electrochemical behavior of trivalent vanadium species was investigated in a Lewis basic 1-ethyl-3-methylimidazolium chloride (EMIC)-aluminum trichloride (AlCl3) molten salt at room temperature. The reduction of V(III) was observed around -1.2 V vs. Al(III) / Al in the cyclic voltammogram on platinum electrode. The reduction process of V(III) seems electrochemically irreversible as observed in aqueous solution.
KW - 1-ethyl-3-methylimidazolium chloride-aluminum trichloride
KW - Vanadium trichloride
UR - http://www.scopus.com/inward/record.url?scp=0009408667&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0009408667&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0009408667
VL - 67
SP - 547
EP - 549
JO - Electrochemistry
JF - Electrochemistry
SN - 1344-3542
IS - 6
ER -