Electrochemical Behavior of Vanadium Trichloride in 1-ethyl-3-methyimidazolium Chloride-Aluminum Trichloride Molten Salt

Yasushi Katayama; Isamu Konishiike; Takashi Miura; Tomiya Kishi

doi:10.5796/electrochemistry.67.547

Electrochemical Behavior of Vanadium Trichloride in 1-ethyl-3-methyimidazolium Chloride-Aluminum Trichloride Molten Salt

Yasushi Katayama, Isamu Konishiike, Takashi Miura, Tomiya Kishi

Department of Applied Chemistry

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

Electrochemical behavior of trivalent vanadium species was investigated in a Lewis basic 1-ethyl-3-methylimidazolium chloride (EMIC)-aluminum trichloride (AlCl₃) molten salt at room temperature. The reduction of V(III) was observed around -1.2 V vs. Al(III) / Al in the cyclic voltammogram on platinum electrode. The reduction process of V(III) seems electrochemically irreversible as observed in aqueous solution.

Original language	English
Pages (from-to)	547-549
Number of pages	3
Journal	Electrochemistry
Volume	67
Issue number	6
DOIs	https://doi.org/10.5796/electrochemistry.67.547
Publication status	Published - 1999

Keywords

1-ethyl-3-methylimidazolium chloride-aluminum trichloride
Vanadium trichloride

ASJC Scopus subject areas

Electrochemistry

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10.5796/electrochemistry.67.547

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title = "Electrochemical Behavior of Vanadium Trichloride in 1-ethyl-3-methyimidazolium Chloride-Aluminum Trichloride Molten Salt",

abstract = "Electrochemical behavior of trivalent vanadium species was investigated in a Lewis basic 1-ethyl-3-methylimidazolium chloride (EMIC)-aluminum trichloride (AlCl3) molten salt at room temperature. The reduction of V(III) was observed around -1.2 V vs. Al(III) / Al in the cyclic voltammogram on platinum electrode. The reduction process of V(III) seems electrochemically irreversible as observed in aqueous solution.",

keywords = "1-ethyl-3-methylimidazolium chloride-aluminum trichloride, Vanadium trichloride",

author = "Yasushi Katayama and Isamu Konishiike and Takashi Miura and Tomiya Kishi",

year = "1999",

doi = "10.5796/electrochemistry.67.547",

language = "English",

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pages = "547--549",

journal = "Electrochemistry",

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T1 - Electrochemical Behavior of Vanadium Trichloride in 1-ethyl-3-methyimidazolium Chloride-Aluminum Trichloride Molten Salt

AU - Katayama, Yasushi

AU - Konishiike, Isamu

AU - Miura, Takashi

AU - Kishi, Tomiya

PY - 1999

Y1 - 1999

N2 - Electrochemical behavior of trivalent vanadium species was investigated in a Lewis basic 1-ethyl-3-methylimidazolium chloride (EMIC)-aluminum trichloride (AlCl3) molten salt at room temperature. The reduction of V(III) was observed around -1.2 V vs. Al(III) / Al in the cyclic voltammogram on platinum electrode. The reduction process of V(III) seems electrochemically irreversible as observed in aqueous solution.

AB - Electrochemical behavior of trivalent vanadium species was investigated in a Lewis basic 1-ethyl-3-methylimidazolium chloride (EMIC)-aluminum trichloride (AlCl3) molten salt at room temperature. The reduction of V(III) was observed around -1.2 V vs. Al(III) / Al in the cyclic voltammogram on platinum electrode. The reduction process of V(III) seems electrochemically irreversible as observed in aqueous solution.

KW - 1-ethyl-3-methylimidazolium chloride-aluminum trichloride

KW - Vanadium trichloride

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JF - Electrochemistry

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Electrochemical Behavior of Vanadium Trichloride in 1-ethyl-3-methyimidazolium Chloride-Aluminum Trichloride Molten Salt

Abstract

Keywords

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