Electrochemical insertion of magnesium to Mg0.5Ti2(PO4)3

Koji Makino, Yasushi Katayama, Takashi Miura, Tomiya Kishi

Research output: Contribution to journalArticle

46 Citations (Scopus)

Abstract

Mg0.5Ti2(PO4)3 having NASICON-lattice was prepared by sol-gel method and evaluated as a cathode material for magnesium cells. The crystalline phase could be successfully obtained after heating at 600°C. Electrochemical magnesium insertion from a propylene carbonate solution into this host was found possible and one Mg2+ ion could be accommodated per unit formula. However, the magnesium insertion process was under kinetic control of Mg2+ diffusion due to the low mobility of Mg2+ in this host.

Original languageEnglish
Pages (from-to)66-69
Number of pages4
JournalJournal of Power Sources
Volume99
Issue number1-2
DOIs
Publication statusPublished - 2001 Aug

Fingerprint

magnesium cells
Magnesium
magnesium
insertion
propylene
carbonates
cathodes
gels
Sol-gel process
Propylene
heating
Carbonates
kinetics
Cathodes
Ions
Crystalline materials
Heating
ions
Kinetics
propylene carbonate

Keywords

  • Electrochemical magnesium insertion
  • Magnesium battery
  • Magnesium titanium phosphate

ASJC Scopus subject areas

  • Electrochemistry
  • Fuel Technology
  • Materials Chemistry

Cite this

Electrochemical insertion of magnesium to Mg0.5Ti2(PO4)3. / Makino, Koji; Katayama, Yasushi; Miura, Takashi; Kishi, Tomiya.

In: Journal of Power Sources, Vol. 99, No. 1-2, 08.2001, p. 66-69.

Research output: Contribution to journalArticle

Makino, Koji ; Katayama, Yasushi ; Miura, Takashi ; Kishi, Tomiya. / Electrochemical insertion of magnesium to Mg0.5Ti2(PO4)3. In: Journal of Power Sources. 2001 ; Vol. 99, No. 1-2. pp. 66-69.
@article{12f61863d77846ea8159ffc9848671ed,
title = "Electrochemical insertion of magnesium to Mg0.5Ti2(PO4)3",
abstract = "Mg0.5Ti2(PO4)3 having NASICON-lattice was prepared by sol-gel method and evaluated as a cathode material for magnesium cells. The crystalline phase could be successfully obtained after heating at 600°C. Electrochemical magnesium insertion from a propylene carbonate solution into this host was found possible and one Mg2+ ion could be accommodated per unit formula. However, the magnesium insertion process was under kinetic control of Mg2+ diffusion due to the low mobility of Mg2+ in this host.",
keywords = "Electrochemical magnesium insertion, Magnesium battery, Magnesium titanium phosphate",
author = "Koji Makino and Yasushi Katayama and Takashi Miura and Tomiya Kishi",
year = "2001",
month = "8",
doi = "10.1016/S0378-7753(01)00480-3",
language = "English",
volume = "99",
pages = "66--69",
journal = "Journal of Power Sources",
issn = "0378-7753",
publisher = "Elsevier",
number = "1-2",

}

TY - JOUR

T1 - Electrochemical insertion of magnesium to Mg0.5Ti2(PO4)3

AU - Makino, Koji

AU - Katayama, Yasushi

AU - Miura, Takashi

AU - Kishi, Tomiya

PY - 2001/8

Y1 - 2001/8

N2 - Mg0.5Ti2(PO4)3 having NASICON-lattice was prepared by sol-gel method and evaluated as a cathode material for magnesium cells. The crystalline phase could be successfully obtained after heating at 600°C. Electrochemical magnesium insertion from a propylene carbonate solution into this host was found possible and one Mg2+ ion could be accommodated per unit formula. However, the magnesium insertion process was under kinetic control of Mg2+ diffusion due to the low mobility of Mg2+ in this host.

AB - Mg0.5Ti2(PO4)3 having NASICON-lattice was prepared by sol-gel method and evaluated as a cathode material for magnesium cells. The crystalline phase could be successfully obtained after heating at 600°C. Electrochemical magnesium insertion from a propylene carbonate solution into this host was found possible and one Mg2+ ion could be accommodated per unit formula. However, the magnesium insertion process was under kinetic control of Mg2+ diffusion due to the low mobility of Mg2+ in this host.

KW - Electrochemical magnesium insertion

KW - Magnesium battery

KW - Magnesium titanium phosphate

UR - http://www.scopus.com/inward/record.url?scp=0035423299&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0035423299&partnerID=8YFLogxK

U2 - 10.1016/S0378-7753(01)00480-3

DO - 10.1016/S0378-7753(01)00480-3

M3 - Article

VL - 99

SP - 66

EP - 69

JO - Journal of Power Sources

JF - Journal of Power Sources

SN - 0378-7753

IS - 1-2

ER -