Electrochemical reaction of bis(acetylacetonate)palladium in an amide-type ionic liquid

Kazuki Yoshii, Yosuke Oshino, Naoki Tachikawa, Kazunobu Toshima, Yasushi Katayama

Research output: Chapter in Book/Report/Conference proceedingConference contribution

1 Citation (Scopus)

Abstract

The electrochemical reaction of bis(acetylacetonato)palladium (Pd(acac)2) was investigated in 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)amide using a rotating ring-disk electrode. Metallic palladium was deposited on the electrode after potentiostatic cathodic reduction at -1.9 V vs. Ag|Ag(I). When the linear sweep voltammetry with maintaining the ring potential at - 1.25 V was conducted, the anodic current of ring electrode was detected at - 1.9 V with the cathodic disk current which is attributed to the reduction of Pd(acac)2. This result suggested that the metallic palladium may be formed by the disproportionation reaction of [Pd(acac)2]-. In addition, Pd nanoparticle was synthesized by the electrochemical reduction in 1-hexyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)amide (HMPTFSA) and 1-decyl-1-methylpyrrolidinium (DMPTFSA) in order to compare the sizes of Pd nanoparticles with that prepared in BMPTFSA. The particle size became small with increasing the alkyl chain length in the cation of ionic liquid.

Original languageEnglish
Title of host publicationMolten Salts and Ionic Liquids 20
PublisherElectrochemical Society Inc.
Pages517-524
Number of pages8
Volume75
Edition15
ISBN (Electronic)9781607685395
DOIs
Publication statusPublished - 2016
EventSymposium on Molten Salts and Ionic Liquids 20 - PRiME 2016/230th ECS Meeting - Honolulu, United States
Duration: 2016 Oct 22016 Oct 7

Other

OtherSymposium on Molten Salts and Ionic Liquids 20 - PRiME 2016/230th ECS Meeting
CountryUnited States
CityHonolulu
Period16/10/216/10/7

ASJC Scopus subject areas

  • Engineering(all)

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