Electrochemically Generated ArS(ArSSAr)+B(C6F 5)4- as an Activator of Thioglycosides for Glycosylation

Kodai Saito, Yoshihiro Saigusa, Toshiki Nokami, Jun Ichi Yoshida

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

Electrochemically generated ArS(ArSSAr)+ was found to be an effective activator for glycosylation of thioglycosides. Efficiency of the reaction strongly depends on the nature of the counter anion, and B(C 6F5)4 - was the most effective among those examined. The method was applicable to various glyocosyl donors including thiogalactosides and thiomannosides and various acceptors including those having secondary hydroxy groups.

Original languageEnglish
Pages (from-to)678-679
Number of pages2
JournalChemistry Letters
Volume40
Issue number7
DOIs
Publication statusPublished - 2011
Externally publishedYes

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Thioglycosides
Thiogalactosides
Glycosylation
Anions

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Electrochemically Generated ArS(ArSSAr)+B(C6F 5)4- as an Activator of Thioglycosides for Glycosylation. / Saito, Kodai; Saigusa, Yoshihiro; Nokami, Toshiki; Yoshida, Jun Ichi.

In: Chemistry Letters, Vol. 40, No. 7, 2011, p. 678-679.

Research output: Contribution to journalArticle

Saito, Kodai ; Saigusa, Yoshihiro ; Nokami, Toshiki ; Yoshida, Jun Ichi. / Electrochemically Generated ArS(ArSSAr)+B(C6F 5)4- as an Activator of Thioglycosides for Glycosylation. In: Chemistry Letters. 2011 ; Vol. 40, No. 7. pp. 678-679.
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