Electrodeposition of palladium in a hydrophobic 1-n-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide room-temperature ionic liquid

Yuri Bando, Yasushi Katayama, Takashi Miura

Research output: Contribution to journalArticle

60 Citations (Scopus)

Abstract

The electrochemical reduction of palladium halide complexes such as PdBr42- and PdCl42- was investigated in a hydrophobic room-temperature ionic liquid (RTIL), 1-n-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide (BMPTFSI). The irreversible electrode reaction between Pd(II) and Pd(0) was observed in BMPTFSI containing PdBr42- or PdCl42- by cyclic voltammetry. The diffusion coefficient of PdBr42- was estimated to be (1-2) × 10-7 cm2 s-1 by choronopotentiometry and chronoamperometry. The deposition of crystalline Pd metal was confirmed by X-ray diffraction and X-ray photoelectron spectroscopy. It was suggested by the chronoamperometric measurements on PdBr42- in BMPTFSI that the initial stage of the electrodeposition of Pd on the polycrystalline Pt electrode surface involves three-dimensional progressive nucleation under diffusion control. The reduction potential of PdCl42- was more negative than that of PdBr42-, reflecting the difference in the donor property between chloride and bromide.

Original languageEnglish
Pages (from-to)87-91
Number of pages5
JournalElectrochimica Acta
Volume53
Issue number1
DOIs
Publication statusPublished - 2007 Nov 20

Fingerprint

Imides
Ionic Liquids
Palladium
Ionic liquids
Electrodeposition
Chronoamperometry
Electrodes
Cyclic voltammetry
Nucleation
X ray photoelectron spectroscopy
Crystalline materials
Bromides
X ray diffraction
Temperature
Chlorides
Metals

Keywords

  • 1-n-Butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide
  • Electrodeposition
  • Electroplating
  • Ionic liquid
  • Palladium

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Analytical Chemistry
  • Electrochemistry

Cite this

Electrodeposition of palladium in a hydrophobic 1-n-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide room-temperature ionic liquid. / Bando, Yuri; Katayama, Yasushi; Miura, Takashi.

In: Electrochimica Acta, Vol. 53, No. 1, 20.11.2007, p. 87-91.

Research output: Contribution to journalArticle

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AB - The electrochemical reduction of palladium halide complexes such as PdBr42- and PdCl42- was investigated in a hydrophobic room-temperature ionic liquid (RTIL), 1-n-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide (BMPTFSI). The irreversible electrode reaction between Pd(II) and Pd(0) was observed in BMPTFSI containing PdBr42- or PdCl42- by cyclic voltammetry. The diffusion coefficient of PdBr42- was estimated to be (1-2) × 10-7 cm2 s-1 by choronopotentiometry and chronoamperometry. The deposition of crystalline Pd metal was confirmed by X-ray diffraction and X-ray photoelectron spectroscopy. It was suggested by the chronoamperometric measurements on PdBr42- in BMPTFSI that the initial stage of the electrodeposition of Pd on the polycrystalline Pt electrode surface involves three-dimensional progressive nucleation under diffusion control. The reduction potential of PdCl42- was more negative than that of PdBr42-, reflecting the difference in the donor property between chloride and bromide.

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