Electrodeposition of platinum in some amide-type ionic liquids containing Bis(acetylacetonato)platinum(II)

Sharmin Sultana, Naoki Tachikawa, Kazuki Yoshii, Luca Magagnin, Yasushi Katayama

Research output: Chapter in Book/Report/Conference proceedingConference contribution

1 Citation (Scopus)

Abstract

Electrodeposition of platinum (Pt) from bis(acetylacetonato)platinum(II) (Pt(acac)2) has been investigated in bis(trifluoromethylsulfonyl)amide (TFSA-) ionic liquids composed of 1-butyl-1-methylpyrrolidinium (BMP+), 1-hexyl-1-methylpyrrolidinium (HMP+) and 1-decyl-1-methylpyrrolidinium (DMP+). Pt(acac)2 was found to be electrochemically reduced to Pt(0) in each ionic liquid. Reduction of Pt(acac)2 was suggested to involve formation and disproportionation of some intermediate species of Pt by cyclic voltammetry. Potentiostatic cathodic reduction at -1.7 V resulted in deposition of Pt and Pt nanoparticles dispersed in the ionic liquid. The average sizes (in diameter) of the Pt nanoparticles were found to be 2.6 ± 0.7, 4.1 ± 1.2 and 4.3 ± 0.7 nm in BMPTFSA, HMPTFSA and DMPTFSA, respectively. The average particle sizes of the Pt nanoparticles tended to increase with an increase in the alkyl chain length of the cations of the ionic liquids.

Original languageEnglish
Title of host publicationMolten Salts and Ionic Liquids 20
EditorsM. Carter, F. Endres, E. J. Biddinger, M. Reichert, A. Ispas, H. C. De Long, A. Bund, L. M. Haverhals, R. A. Mantz, P. C. Trulove, D. M. Fox, A. H. Suroviec, M. Ueda
PublisherElectrochemical Society Inc.
Pages617-625
Number of pages9
Edition15
ISBN (Electronic)9781607685395
DOIs
Publication statusPublished - 2016 Jan 1
EventSymposium on Molten Salts and Ionic Liquids 20 - PRiME 2016/230th ECS Meeting - Honolulu, United States
Duration: 2016 Oct 22016 Oct 7

Publication series

NameECS Transactions
Number15
Volume75
ISSN (Print)1938-5862
ISSN (Electronic)1938-6737

Other

OtherSymposium on Molten Salts and Ionic Liquids 20 - PRiME 2016/230th ECS Meeting
CountryUnited States
CityHonolulu
Period16/10/216/10/7

ASJC Scopus subject areas

  • Engineering(all)

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    Sultana, S., Tachikawa, N., Yoshii, K., Magagnin, L., & Katayama, Y. (2016). Electrodeposition of platinum in some amide-type ionic liquids containing Bis(acetylacetonato)platinum(II). In M. Carter, F. Endres, E. J. Biddinger, M. Reichert, A. Ispas, H. C. De Long, A. Bund, L. M. Haverhals, R. A. Mantz, P. C. Trulove, D. M. Fox, A. H. Suroviec, & M. Ueda (Eds.), Molten Salts and Ionic Liquids 20 (15 ed., pp. 617-625). (ECS Transactions; Vol. 75, No. 15). Electrochemical Society Inc.. https://doi.org/10.1149/07515.0617ecst