Electrodeposition of tin in an amide type ionic liquid containing chloride ion

Maoko Sano; Naoki Tachikawa; Kazuki Yoshii; Nobuyuki Serizawa; Yasushi Katayama

doi:10.5796/electrochemistry.18-00033

Electrodeposition of tin in an amide type ionic liquid containing chloride ion

Maoko Sano, Naoki Tachikawa, Kazuki Yoshii, Nobuyuki Serizawa, Yasushi Katayama

Department of Applied Chemistry

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

Electrochemical behavior of Sn was investigated on a GC electrode in an aprotic ionic liquid, 1-butyl-1- methylpyrrolidinium bis(trifluoromethylsulfonyl)amide (BMPTFSA) containing BMPCl and SnCl₂ at 298K. SnCl₂ was found to dissolve as [SnCl₄]^2- by potentiometry. The formal potential of [SnCl₄]^2-/Sn was -1.67V vs. Ag|Ag(I) (-1.24V vs. ferrocene|ferrocenium), which was more negative than that in BMPTFSA without chloride ions. Electrodeposition of Sn was possible by reduction of [SnCl₄]^2- in the ionic liquid. The dissociation of [SnCl₄]^2- was suggested from the diffusion coefficient of [SnCl₄]^2-. Tubular deposits with an inner diameter of 1-1.5μm were obtained in addition to granular deposits by potentiostatic cathodic reduction at -2.0V.

Original language	English
Pages (from-to)	260-264
Number of pages	5
Journal	Electrochemistry
Volume	86
Issue number	5
DOIs	https://doi.org/10.5796/electrochemistry.18-00033
Publication status	Published - 2018

Keywords

Chlorocomplex
Electrodeposition
Ionic liquid
Tin

ASJC Scopus subject areas

Electrochemistry

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10.5796/electrochemistry.18-00033

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title = "Electrodeposition of tin in an amide type ionic liquid containing chloride ion",

abstract = "Electrochemical behavior of Sn was investigated on a GC electrode in an aprotic ionic liquid, 1-butyl-1- methylpyrrolidinium bis(trifluoromethylsulfonyl)amide (BMPTFSA) containing BMPCl and SnCl2 at 298K. SnCl2 was found to dissolve as [SnCl4]2- by potentiometry. The formal potential of [SnCl4]2-/Sn was -1.67V vs. Ag|Ag(I) (-1.24V vs. ferrocene|ferrocenium), which was more negative than that in BMPTFSA without chloride ions. Electrodeposition of Sn was possible by reduction of [SnCl4]2- in the ionic liquid. The dissociation of [SnCl4]2- was suggested from the diffusion coefficient of [SnCl4]2-. Tubular deposits with an inner diameter of 1-1.5μm were obtained in addition to granular deposits by potentiostatic cathodic reduction at -2.0V.",

keywords = "Chlorocomplex, Electrodeposition, Ionic liquid, Tin",

author = "Maoko Sano and Naoki Tachikawa and Kazuki Yoshii and Nobuyuki Serizawa and Yasushi Katayama",

year = "2018",

doi = "10.5796/electrochemistry.18-00033",

language = "English",

volume = "86",

pages = "260--264",

journal = "Electrochemistry",

issn = "1344-3542",

publisher = "Electrochemical Society of Japan",

number = "5",

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TY - JOUR

T1 - Electrodeposition of tin in an amide type ionic liquid containing chloride ion

AU - Sano, Maoko

AU - Tachikawa, Naoki

AU - Yoshii, Kazuki

AU - Serizawa, Nobuyuki

AU - Katayama, Yasushi

PY - 2018

Y1 - 2018

N2 - Electrochemical behavior of Sn was investigated on a GC electrode in an aprotic ionic liquid, 1-butyl-1- methylpyrrolidinium bis(trifluoromethylsulfonyl)amide (BMPTFSA) containing BMPCl and SnCl2 at 298K. SnCl2 was found to dissolve as [SnCl4]2- by potentiometry. The formal potential of [SnCl4]2-/Sn was -1.67V vs. Ag|Ag(I) (-1.24V vs. ferrocene|ferrocenium), which was more negative than that in BMPTFSA without chloride ions. Electrodeposition of Sn was possible by reduction of [SnCl4]2- in the ionic liquid. The dissociation of [SnCl4]2- was suggested from the diffusion coefficient of [SnCl4]2-. Tubular deposits with an inner diameter of 1-1.5μm were obtained in addition to granular deposits by potentiostatic cathodic reduction at -2.0V.

AB - Electrochemical behavior of Sn was investigated on a GC electrode in an aprotic ionic liquid, 1-butyl-1- methylpyrrolidinium bis(trifluoromethylsulfonyl)amide (BMPTFSA) containing BMPCl and SnCl2 at 298K. SnCl2 was found to dissolve as [SnCl4]2- by potentiometry. The formal potential of [SnCl4]2-/Sn was -1.67V vs. Ag|Ag(I) (-1.24V vs. ferrocene|ferrocenium), which was more negative than that in BMPTFSA without chloride ions. Electrodeposition of Sn was possible by reduction of [SnCl4]2- in the ionic liquid. The dissociation of [SnCl4]2- was suggested from the diffusion coefficient of [SnCl4]2-. Tubular deposits with an inner diameter of 1-1.5μm were obtained in addition to granular deposits by potentiostatic cathodic reduction at -2.0V.

KW - Chlorocomplex

KW - Electrodeposition

KW - Ionic liquid

KW - Tin

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U2 - 10.5796/electrochemistry.18-00033

DO - 10.5796/electrochemistry.18-00033

M3 - Article

AN - SCOPUS:85053834592

SN - 1344-3542

VL - 86

SP - 260

EP - 264

JO - Electrochemistry

JF - Electrochemistry

IS - 5

ER -

Electrodeposition of tin in an amide type ionic liquid containing chloride ion

Abstract

Keywords

ASJC Scopus subject areas

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