Electronic conductivity in Berlin green and Prussian blue

Daniel M. Pajerowski, Takeshi Watanabe, Takashi Yamamoto, Yasuaki Einaga

Research output: Contribution to journalArticlepeer-review

30 Citations (Scopus)

Abstract

We report the temperature dependent (100-300 K) conductivity of Berlin green and Prussian blue powders. The method of electronic conduction in vacuum dried Berlin green is identified as hopping of localized electrons and vacuum dried Prussian blue is reaffirmed as an insulator. The assignment of the conduction mechanism is based upon fits to the experimental data, and the different conductivities of the two samples can be understood in terms of both molecular and simple crystalline energy levels of the solids.

Original languageEnglish
Article number153202
JournalPhysical Review B - Condensed Matter and Materials Physics
Volume83
Issue number15
DOIs
Publication statusPublished - 2011 Apr 18

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics

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