Electronic spectra of p-dicyanobenzene (p-DCNB), p-DCNB-H2O complex, and p-DCNB dimer in a supersonic jet

Keiko Fujita, Takashige Fujiwara, Kentaro Matsunaga, Fuminobu Ono, Atsushi Nakajima, Hironao Watanabe, Tomohisa Koguchi, Isamu Suzuka, Hidenori Matsuzawa, Suehiro Iwata, Koji Kaya

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Abstract

S1-S0 electronic spectra of jet-cooled p-dicyanobenzene (p-DCNB), its H2O complex, and the dimer ((p-DCNB)2) were recorded using laser-induced fluorescence and two-color multiphoton ionization methods. Several vibrational bands in S1 of the monomer were assigned to the corresponding vibrational modes in the ground S0 state. Geometric structures of p-DCNB-H2O and (p-DCNB)2 were determined by the analyses of rotational envelopes of the vibronic bands of these complexes.

Original languageEnglish
Pages (from-to)10693-10697
Number of pages5
JournalJournal of Physical Chemistry
Volume96
Issue number26
Publication statusPublished - 1992

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electronic spectra
Dimers
Ground state
Ionization
Monomers
Fluorescence
dimers
Color
Lasers
laser induced fluorescence
vibration mode
envelopes
monomers
color
ionization
ground state
1,2,4,5-tetracyanobenzene

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

Cite this

Fujita, K., Fujiwara, T., Matsunaga, K., Ono, F., Nakajima, A., Watanabe, H., ... Kaya, K. (1992). Electronic spectra of p-dicyanobenzene (p-DCNB), p-DCNB-H2O complex, and p-DCNB dimer in a supersonic jet. Journal of Physical Chemistry, 96(26), 10693-10697.

Electronic spectra of p-dicyanobenzene (p-DCNB), p-DCNB-H2O complex, and p-DCNB dimer in a supersonic jet. / Fujita, Keiko; Fujiwara, Takashige; Matsunaga, Kentaro; Ono, Fuminobu; Nakajima, Atsushi; Watanabe, Hironao; Koguchi, Tomohisa; Suzuka, Isamu; Matsuzawa, Hidenori; Iwata, Suehiro; Kaya, Koji.

In: Journal of Physical Chemistry, Vol. 96, No. 26, 1992, p. 10693-10697.

Research output: Contribution to journalArticle

Fujita, K, Fujiwara, T, Matsunaga, K, Ono, F, Nakajima, A, Watanabe, H, Koguchi, T, Suzuka, I, Matsuzawa, H, Iwata, S & Kaya, K 1992, 'Electronic spectra of p-dicyanobenzene (p-DCNB), p-DCNB-H2O complex, and p-DCNB dimer in a supersonic jet', Journal of Physical Chemistry, vol. 96, no. 26, pp. 10693-10697.
Fujita, Keiko ; Fujiwara, Takashige ; Matsunaga, Kentaro ; Ono, Fuminobu ; Nakajima, Atsushi ; Watanabe, Hironao ; Koguchi, Tomohisa ; Suzuka, Isamu ; Matsuzawa, Hidenori ; Iwata, Suehiro ; Kaya, Koji. / Electronic spectra of p-dicyanobenzene (p-DCNB), p-DCNB-H2O complex, and p-DCNB dimer in a supersonic jet. In: Journal of Physical Chemistry. 1992 ; Vol. 96, No. 26. pp. 10693-10697.
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AU - Fujita, Keiko

AU - Fujiwara, Takashige

AU - Matsunaga, Kentaro

AU - Ono, Fuminobu

AU - Nakajima, Atsushi

AU - Watanabe, Hironao

AU - Koguchi, Tomohisa

AU - Suzuka, Isamu

AU - Matsuzawa, Hidenori

AU - Iwata, Suehiro

AU - Kaya, Koji

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