Electronic spectra of p-dicyanobenzene (p-DCNB), p-DCNB-H2O complex, and p-DCNB dimer in a supersonic jet

Keiko Fujita, Takashige Fujiwara, Kentaro Matsunaga, Fuminobu Ono, Atsushi Nakajima, Hironao Watanabe, Tomohisa Koguchi, Isamu Suzuka, Hidenori Matsuzawa, Suehiro Iwata, Koji Kaya

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5 Citations (Scopus)

Abstract

S1-S0 electronic spectra of jet-cooled p-dicyanobenzene (p-DCNB), its H2O complex, and the dimer ((p-DCNB)2) were recorded using laser-induced fluorescence and two-color multiphoton ionization methods. Several vibrational bands in S1 of the monomer were assigned to the corresponding vibrational modes in the ground S0 state. Geometric structures of p-DCNB-H2O and (p-DCNB)2 were determined by the analyses of rotational envelopes of the vibronic bands of these complexes.

Original languageEnglish
Pages (from-to)10693-10697
Number of pages5
JournalJournal of Physical Chemistry
Volume96
Issue number26
DOIs
Publication statusPublished - 1992

ASJC Scopus subject areas

  • Engineering(all)
  • Physical and Theoretical Chemistry

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    Fujita, K., Fujiwara, T., Matsunaga, K., Ono, F., Nakajima, A., Watanabe, H., Koguchi, T., Suzuka, I., Matsuzawa, H., Iwata, S., & Kaya, K. (1992). Electronic spectra of p-dicyanobenzene (p-DCNB), p-DCNB-H2O complex, and p-DCNB dimer in a supersonic jet. Journal of Physical Chemistry, 96(26), 10693-10697. https://doi.org/10.1021/j100205a023