Electronic structures of highly deformed iron(III) porphyrin complexes

Mikio Nakamura

Research output: Contribution to journalArticle

144 Citations (Scopus)

Abstract

This review describes the effects of highly deformed porphyrin ring on the electronic structures of iron(III) porphyrinates, which includes (i) the electron configurations in low-spin (S = 1/2) ruffled complexes, (ii) the contribution of the intermediate-spin (S = 3/2) state in the spin-admixed (S = 5/2, 3/2) complexes with ruffled and saddled porphyrin ring, and (iii) the novel spin crossover (S = 1/2, S = 3/2) phenomenon in saddled complexes, with a special emphasis on the use of 1H NMR, 13C NMR, and EPR spectroscopy.

Original languageEnglish
Pages (from-to)2271-2294
Number of pages24
JournalCoordination Chemistry Reviews
Volume250
Issue number17-18
DOIs
Publication statusPublished - 2006 Sep

Fingerprint

Porphyrins
porphyrins
Electronic structure
Iron
Nuclear magnetic resonance
electronic structure
iron
Paramagnetic resonance
Spectroscopy
nuclear magnetic resonance
Electrons
rings
crossovers
configurations
spectroscopy
electrons

Keywords

  • Deformation
  • Electronic structures
  • EPR
  • Iron(III)
  • NMR
  • Porphyrin
  • Spin crossover

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

Cite this

Electronic structures of highly deformed iron(III) porphyrin complexes. / Nakamura, Mikio.

In: Coordination Chemistry Reviews, Vol. 250, No. 17-18, 09.2006, p. 2271-2294.

Research output: Contribution to journalArticle

Nakamura, Mikio. / Electronic structures of highly deformed iron(III) porphyrin complexes. In: Coordination Chemistry Reviews. 2006 ; Vol. 250, No. 17-18. pp. 2271-2294.
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