Electronic structures of highly deformed iron(III) porphyrin complexes

Mikio Nakamura

Research output: Contribution to journalReview articlepeer-review

158 Citations (Scopus)

Abstract

This review describes the effects of highly deformed porphyrin ring on the electronic structures of iron(III) porphyrinates, which includes (i) the electron configurations in low-spin (S = 1/2) ruffled complexes, (ii) the contribution of the intermediate-spin (S = 3/2) state in the spin-admixed (S = 5/2, 3/2) complexes with ruffled and saddled porphyrin ring, and (iii) the novel spin crossover (S = 1/2, S = 3/2) phenomenon in saddled complexes, with a special emphasis on the use of 1H NMR, 13C NMR, and EPR spectroscopy.

Original languageEnglish
Pages (from-to)2271-2294
Number of pages24
JournalCoordination Chemistry Reviews
Volume250
Issue number17-18
DOIs
Publication statusPublished - 2006 Sep

Keywords

  • Deformation
  • EPR
  • Electronic structures
  • Iron(III)
  • NMR
  • Porphyrin
  • Spin crossover

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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