Abstract
This review describes the effects of highly deformed porphyrin ring on the electronic structures of iron(III) porphyrinates, which includes (i) the electron configurations in low-spin (S = 1/2) ruffled complexes, (ii) the contribution of the intermediate-spin (S = 3/2) state in the spin-admixed (S = 5/2, 3/2) complexes with ruffled and saddled porphyrin ring, and (iii) the novel spin crossover (S = 1/2, S = 3/2) phenomenon in saddled complexes, with a special emphasis on the use of 1H NMR, 13C NMR, and EPR spectroscopy.
| Original language | English |
|---|---|
| Pages (from-to) | 2271-2294 |
| Number of pages | 24 |
| Journal | Coordination Chemistry Reviews |
| Volume | 250 |
| Issue number | 17-18 |
| DOIs | |
| Publication status | Published - 2006 Sep |
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Keywords
- Deformation
- Electronic structures
- EPR
- Iron(III)
- NMR
- Porphyrin
- Spin crossover
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
Cite this
Electronic structures of highly deformed iron(III) porphyrin complexes. / Nakamura, Mikio.
In: Coordination Chemistry Reviews, Vol. 250, No. 17-18, 09.2006, p. 2271-2294.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Electronic structures of highly deformed iron(III) porphyrin complexes
AU - Nakamura, Mikio
PY - 2006/9
Y1 - 2006/9
N2 - This review describes the effects of highly deformed porphyrin ring on the electronic structures of iron(III) porphyrinates, which includes (i) the electron configurations in low-spin (S = 1/2) ruffled complexes, (ii) the contribution of the intermediate-spin (S = 3/2) state in the spin-admixed (S = 5/2, 3/2) complexes with ruffled and saddled porphyrin ring, and (iii) the novel spin crossover (S = 1/2, S = 3/2) phenomenon in saddled complexes, with a special emphasis on the use of 1H NMR, 13C NMR, and EPR spectroscopy.
AB - This review describes the effects of highly deformed porphyrin ring on the electronic structures of iron(III) porphyrinates, which includes (i) the electron configurations in low-spin (S = 1/2) ruffled complexes, (ii) the contribution of the intermediate-spin (S = 3/2) state in the spin-admixed (S = 5/2, 3/2) complexes with ruffled and saddled porphyrin ring, and (iii) the novel spin crossover (S = 1/2, S = 3/2) phenomenon in saddled complexes, with a special emphasis on the use of 1H NMR, 13C NMR, and EPR spectroscopy.
KW - Deformation
KW - Electronic structures
KW - EPR
KW - Iron(III)
KW - NMR
KW - Porphyrin
KW - Spin crossover
UR - http://www.scopus.com/inward/record.url?scp=33746872140&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=33746872140&partnerID=8YFLogxK
U2 - 10.1016/j.ccr.2006.03.001
DO - 10.1016/j.ccr.2006.03.001
M3 - Article
AN - SCOPUS:33746872140
VL - 250
SP - 2271
EP - 2294
JO - Coordination Chemistry Reviews
JF - Coordination Chemistry Reviews
SN - 0010-8545
IS - 17-18
ER -