Abstract
This review describes the effects of highly deformed porphyrin ring on the electronic structures of iron(III) porphyrinates, which includes (i) the electron configurations in low-spin (S = 1/2) ruffled complexes, (ii) the contribution of the intermediate-spin (S = 3/2) state in the spin-admixed (S = 5/2, 3/2) complexes with ruffled and saddled porphyrin ring, and (iii) the novel spin crossover (S = 1/2, S = 3/2) phenomenon in saddled complexes, with a special emphasis on the use of 1H NMR, 13C NMR, and EPR spectroscopy.
| Original language | English |
|---|---|
| Pages (from-to) | 2271-2294 |
| Number of pages | 24 |
| Journal | Coordination Chemistry Reviews |
| Volume | 250 |
| Issue number | 17-18 |
| DOIs | |
| Publication status | Published - 2006 Sep |
Keywords
- Deformation
- EPR
- Electronic structures
- Iron(III)
- NMR
- Porphyrin
- Spin crossover
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry
- Materials Chemistry
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Cite this
Nakamura, M. (2006). Electronic structures of highly deformed iron(III) porphyrin complexes. Coordination Chemistry Reviews, 250(17-18), 2271-2294. https://doi.org/10.1016/j.ccr.2006.03.001