Enantioselective ene reaction of cyclopentadiene and α,β-enals catalyzed by a diphenylprolinol silyl ether

Hiroaki Gotoh, Ryouhei Masui, Hiroshi Ogino, Mitsuru Shoji, Yujiro Hayashi

Research output: Contribution to journalArticle

87 Citations (Scopus)

Abstract

(Chemical Equation Presented) The opposite result: A diphenylprolinol silyl ether promotes an intermolecular enantioselective ene reaction of α,β-enals with cyclopentadiene. This is the first example of cyclopentadiene acting as the ene component, and not the diene, with α,β-enals.

Original languageEnglish
Pages (from-to)6853-6856
Number of pages4
JournalAngewandte Chemie - International Edition
Volume45
Issue number41
DOIs
Publication statusPublished - 2006 Oct 20

Keywords

  • Asymmetric synthesis
  • Cyclopentadiene
  • Diels-Alder reaction
  • Ene reaction
  • Organocatalysis

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

Fingerprint Dive into the research topics of 'Enantioselective ene reaction of cyclopentadiene and α,β-enals catalyzed by a diphenylprolinol silyl ether'. Together they form a unique fingerprint.

  • Cite this