Enantiospecific Synthesis of the 14-Membered Diene Unit of Methyl Sarcophytoate

Minoru Yasuda, Mitsuaki Ide, Yuka Matsumoto, Masaya Nakata

Research output: Contribution to journalArticle

31 Citations (Scopus)

Abstract

The enantiospecific synthesis of the 14-membered diene unit of methyl sarcophytoate has been achieved by using the Sharpless asymmetric epoxidation, the aldol reaction, the oxy-Michael addition, and the modified Ito-Kodama cyclization as the key steps. All the carbon skeleton was derived from geraniol only.

Original languageEnglish
Pages (from-to)899-902
Number of pages4
JournalSynlett
Volume1997
Issue number8
Publication statusPublished - 1997

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Epoxidation
Cyclization
Carbon
methyl sarcophytoate
3-hydroxybutanal
geraniol

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

Yasuda, M., Ide, M., Matsumoto, Y., & Nakata, M. (1997). Enantiospecific Synthesis of the 14-Membered Diene Unit of Methyl Sarcophytoate. Synlett, 1997(8), 899-902.

Enantiospecific Synthesis of the 14-Membered Diene Unit of Methyl Sarcophytoate. / Yasuda, Minoru; Ide, Mitsuaki; Matsumoto, Yuka; Nakata, Masaya.

In: Synlett, Vol. 1997, No. 8, 1997, p. 899-902.

Research output: Contribution to journalArticle

Yasuda, M, Ide, M, Matsumoto, Y & Nakata, M 1997, 'Enantiospecific Synthesis of the 14-Membered Diene Unit of Methyl Sarcophytoate', Synlett, vol. 1997, no. 8, pp. 899-902.
Yasuda M, Ide M, Matsumoto Y, Nakata M. Enantiospecific Synthesis of the 14-Membered Diene Unit of Methyl Sarcophytoate. Synlett. 1997;1997(8):899-902.
Yasuda, Minoru ; Ide, Mitsuaki ; Matsumoto, Yuka ; Nakata, Masaya. / Enantiospecific Synthesis of the 14-Membered Diene Unit of Methyl Sarcophytoate. In: Synlett. 1997 ; Vol. 1997, No. 8. pp. 899-902.
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