endo-{6,6′-Diethoxy-2,2′-[(R)-propane-1,2- diylbis(nitrilomethylidene)]diphenolato-O,N,N′,O′}oxovanadium(IV)

Gakuse Hoshina, Masanobu Tsuchimoto, Shigeru Ohba

Research output: Contribution to journalArticlepeer-review

14 Citations (Scopus)

Abstract

In the title mononuclear oxovanadium(IV) complex, [VO(C21H24N2O4)], the methyl group of the central diamine moiety in the Schiff base ligand is directed opposite to the oxo ligand. This endo isomer elutes more slowly than the exo isomer when subjected to high-performance liquid reversed-phase chromatography using CH3CN-H2O (1:1 v/v) as the eluent. Crystals of both the endo and exo isomers decompose at 473 K, with no solid-state isomerization from endo to exo or vice versa.

Original languageEnglish
Pages (from-to)1812-1813
Number of pages2
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume55
Issue number11
DOIs
Publication statusPublished - 1999 Nov 15

ASJC Scopus subject areas

  • Biochemistry, Genetics and Molecular Biology(all)

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