@article{5d39aa753b6e474ea40296d41ff57752,
title = "Enhanced oxygen reduction activity of platinum subnanocluster catalysts through charge redistribution",
abstract = "Single-size platinum Pt6 subnanoclusters exhibit superior mass-specific and surface-specific activities for the oxygen reduction reaction. The enhanced activity is attributed to polarized electron distributions based on rigorous structure characterization by X-ray absorption fine structure spectroscopy and density functional theory.",
author = "Hironori Tsunoyama and Akira Ohnuma and Koki Takahashi and Archana Velloth and Masahiro Ehara and Nobuyuki Ichikuni and Masao Tabuchi and Atsushi Nakajima",
note = "Funding Information: The authors thank Dr Tomoyuki Nagai for the advice on electrochemical measurements, Dr Kouta Iwasaki for discussion and comments on the manuscript, Mr Motoki Kondo for the experimental support, and Prof. Dr Hidehiro Yasuda and Prof. Dr Kazuhisa Sato for STEM measurements. Development on nanojimas apparatus was supported by Ayabo Corp. The computations were partly performed using Research Center for Computational Science, Okazaki, Japan. HAADF-STEM measurements were supported by {\textquoteleft}{\textquoteleft}Advanced Characterization Nanotechnology Platform, Nanotechnology Platform Program of the Ministry of Education, Culture, Sports, Science and Technology (MEXT), Japan{\textquoteright}{\textquoteright} at the Research Center for Ultra-High Voltage Electron Microscopy (Nanotechnology Open Facilities) in Osaka University. This work is partly supported by JSPS KAKENHI of Grants-in-Aid for Scientific Research (A) Grant No. 15H02002 and 19H00890, of Challenging Research (Pioneering) Grant No. 17H06226, and of Grant-in-Aid for Young Scientists (A) Grant No. 15H05475. Publisher Copyright: This journal is {\textcopyright} The Royal Society of Chemistry.",
year = "2019",
doi = "10.1039/c9cc06327g",
language = "English",
volume = "55",
pages = "12603--12606",
journal = "Chemical Communications",
issn = "1359-7345",
publisher = "Royal Society of Chemistry",
number = "84",
}