Environmentally benign β-stereoselective glycosidations of glycosyl phosphites using a reusable heterogeneous solid acid, montmorillonite K-10

Hideyuki Nagai, Kaname Sasaki, Shuichi Matsumura, Kazunobu Toshima

Research output: Contribution to journalArticle

45 Citations (Scopus)

Abstract

Environmentally benign and stereoselective β-glycosidations of glycopyranosyl phosphites and alcohols using a reusable heterogeneous solid acid, montmorillonite K-10, as an activator have been developed. By these glycosidations, β-gluco-, 2-deoxy-β-gluco-, and β- mannopyranosides were selectively produced in good to high yields.

Original languageEnglish
Pages (from-to)337-353
Number of pages17
JournalCarbohydrate Research
Volume340
Issue number3
DOIs
Publication statusPublished - 2005 Feb 28

Keywords

  • Glycosidation
  • Glycosyl phosphite
  • Heterogeneous solid acid
  • Montmorillonite K-10

ASJC Scopus subject areas

  • Analytical Chemistry
  • Biochemistry
  • Organic Chemistry

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