TY - JOUR
T1 - Environmentally benign β-stereoselective glycosidations of glycosyl phosphites using a reusable heterogeneous solid acid, montmorillonite K-10
AU - Nagai, Hideyuki
AU - Sasaki, Kaname
AU - Matsumura, Shuichi
AU - Toshima, Kazunobu
N1 - Funding Information:
This research was supported in part by Grant-in-Aid for the 21st Century COE program ‘KEIO Life Conjugate Chemistry’ from the Ministry of Education, Culture, Sports, Science, and Technology, Japan.
PY - 2005/2/28
Y1 - 2005/2/28
N2 - Environmentally benign and stereoselective β-glycosidations of glycopyranosyl phosphites and alcohols using a reusable heterogeneous solid acid, montmorillonite K-10, as an activator have been developed. By these glycosidations, β-gluco-, 2-deoxy-β-gluco-, and β- mannopyranosides were selectively produced in good to high yields.
AB - Environmentally benign and stereoselective β-glycosidations of glycopyranosyl phosphites and alcohols using a reusable heterogeneous solid acid, montmorillonite K-10, as an activator have been developed. By these glycosidations, β-gluco-, 2-deoxy-β-gluco-, and β- mannopyranosides were selectively produced in good to high yields.
KW - Glycosidation
KW - Glycosyl phosphite
KW - Heterogeneous solid acid
KW - Montmorillonite K-10
UR - http://www.scopus.com/inward/record.url?scp=13244275046&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=13244275046&partnerID=8YFLogxK
U2 - 10.1016/j.carres.2004.11.025
DO - 10.1016/j.carres.2004.11.025
M3 - Article
C2 - 15680589
AN - SCOPUS:13244275046
SN - 0008-6215
VL - 340
SP - 337
EP - 353
JO - Carbohydrate Research
JF - Carbohydrate Research
IS - 3
ER -