Environmentally benign and stereoselective formation of β-mannosidic linkages utilizing 2,3-di-O-benzyl-4,6-O-benzylidene-protected mannopyranosyl phosphite and montmorillonite K-10

Hideyuki Nagai, Shuichi Matsumura, Kazunobu Toshima

Research output: Contribution to journalArticle

19 Citations (Scopus)

Abstract

An environmentally benign and stereoselective β-mannopyranosylation has been developed employing 4,6-O-benzylidene-protected mannopyranosyl diethyl phosphite as a glycosyl donor and montmorillonite K-10 as an activator.

Original languageEnglish
Pages (from-to)1531-1534
Number of pages4
JournalCarbohydrate Research
Volume338
Issue number15
DOIs
Publication statusPublished - 2003 Jul 22

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Phosphites
montmorillonite K-10
2,3-di-O-benzyl-4,6-O-benzylidene mannopyranosyl phosphite

Keywords

  • β-Mannopyranoside
  • Glycosidation
  • Glycosyl phosphite
  • Montmorillonite K-10
  • Solid acid

ASJC Scopus subject areas

  • Biochemistry
  • Molecular Biology
  • Organic Chemistry

Cite this

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abstract = "An environmentally benign and stereoselective β-mannopyranosylation has been developed employing 4,6-O-benzylidene-protected mannopyranosyl diethyl phosphite as a glycosyl donor and montmorillonite K-10 as an activator.",
keywords = "β-Mannopyranoside, Glycosidation, Glycosyl phosphite, Montmorillonite K-10, Solid acid",
author = "Hideyuki Nagai and Shuichi Matsumura and Kazunobu Toshima",
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AU - Nagai, Hideyuki

AU - Matsumura, Shuichi

AU - Toshima, Kazunobu

PY - 2003/7/22

Y1 - 2003/7/22

N2 - An environmentally benign and stereoselective β-mannopyranosylation has been developed employing 4,6-O-benzylidene-protected mannopyranosyl diethyl phosphite as a glycosyl donor and montmorillonite K-10 as an activator.

AB - An environmentally benign and stereoselective β-mannopyranosylation has been developed employing 4,6-O-benzylidene-protected mannopyranosyl diethyl phosphite as a glycosyl donor and montmorillonite K-10 as an activator.

KW - β-Mannopyranoside

KW - Glycosidation

KW - Glycosyl phosphite

KW - Montmorillonite K-10

KW - Solid acid

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