Environmentally benign and stereoselective formation of β-mannosidic linkages utilizing 2,3-di-O-benzyl-4,6-O-benzylidene-protected mannopyranosyl phosphite and montmorillonite K-10

Hideyuki Nagai, Shuichi Matsumura, Kazunobu Toshima

Research output: Contribution to journalArticle

19 Citations (Scopus)

Abstract

An environmentally benign and stereoselective β-mannopyranosylation has been developed employing 4,6-O-benzylidene-protected mannopyranosyl diethyl phosphite as a glycosyl donor and montmorillonite K-10 as an activator.

Original languageEnglish
Pages (from-to)1531-1534
Number of pages4
JournalCarbohydrate Research
Volume338
Issue number15
DOIs
Publication statusPublished - 2003 Jul 22

Keywords

  • Glycosidation
  • Glycosyl phosphite
  • Montmorillonite K-10
  • Solid acid
  • β-Mannopyranoside

ASJC Scopus subject areas

  • Analytical Chemistry
  • Biochemistry
  • Organic Chemistry

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