Environmentally benign and stereoselective formation of β-O-glycosidic linkages using benzyl-protected glucopyranosyl phosphite and montmorillonite K-10

Hideyuki Nagai, Shuichi Matsumura, Kazunobu Toshima

Research output: Contribution to journalArticlepeer-review

26 Citations (Scopus)

Abstract

An environmentally benign and highly stereoselective β-glucopyranosylation without neighboring group participation has been developed employing benzyl-protected glucopyranosyl diethyl phosphite as a glycosyl donor and montmorillonite K-10 as an activator.

Original languageEnglish
Pages (from-to)847-850
Number of pages4
JournalTetrahedron Letters
Volume43
Issue number5
DOIs
Publication statusPublished - 2002 Jan 28

Keywords

  • Glycosidation
  • Glycosyl phosphite
  • Montmorillonite K-10
  • Solid acid
  • β-Glucopyranoside

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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