Environmentally benign and stereoselective formation of β-O-glycosidic linkages using benzyl-protected glucopyranosyl phosphite and montmorillonite K-10

Hideyuki Nagai; Shuichi Matsumura; Kazunobu Toshima

doi:10.1016/S0040-4039(01)02252-3

Environmentally benign and stereoselective formation of β-O-glycosidic linkages using benzyl-protected glucopyranosyl phosphite and montmorillonite K-10

Hideyuki Nagai, Shuichi Matsumura, Kazunobu Toshima

Department of Applied Chemistry

Research output: Contribution to journal › Article

26 Citations (Scopus)

Abstract

An environmentally benign and highly stereoselective β-glucopyranosylation without neighboring group participation has been developed employing benzyl-protected glucopyranosyl diethyl phosphite as a glycosyl donor and montmorillonite K-10 as an activator.

Original language	English
Pages (from-to)	847-850
Number of pages	4
Journal	Tetrahedron Letters
Volume	43
Issue number	5
DOIs	https://doi.org/10.1016/S0040-4039(01)02252-3
Publication status	Published - 2002 Jan 28

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Keywords

Glycosidation
Glycosyl phosphite
Montmorillonite K-10
Solid acid
β-Glucopyranoside

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

Cite this

Nagai, H., Matsumura, S., & Toshima, K. (2002). Environmentally benign and stereoselective formation of β-O-glycosidic linkages using benzyl-protected glucopyranosyl phosphite and montmorillonite K-10. Tetrahedron Letters, 43(5), 847-850. https://doi.org/10.1016/S0040-4039(01)02252-3

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10.1016/S0040-4039(01)02252-3