Environmentally benign and stereoselective formation of β-O-glycosidic linkages using benzyl-protected glucopyranosyl phosphite and montmorillonite K-10

Hideyuki Nagai, Shuichi Matsumura, Kazunobu Toshima

Research output: Contribution to journal › Article

26 Citations (Scopus)

Abstract

An environmentally benign and highly stereoselective β-glucopyranosylation without neighboring group participation has been developed employing benzyl-protected glucopyranosyl diethyl phosphite as a glycosyl donor and montmorillonite K-10 as an activator.

Original languageEnglish
Pages (from-to)847-850
Number of pages4
JournalTetrahedron Letters
Volume43
Issue number5
DOIs
Publication statusPublished - 2002 Jan 28

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Phosphites
montmorillonite K-10

Keywords

  • β-Glucopyranoside
  • Glycosidation
  • Glycosyl phosphite
  • Montmorillonite K-10
  • Solid acid

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

Cite this

Environmentally benign and stereoselective formation of β-O-glycosidic linkages using benzyl-protected glucopyranosyl phosphite and montmorillonite K-10. / Nagai, Hideyuki; Matsumura, Shuichi; Toshima, Kazunobu.

In: Tetrahedron Letters, Vol. 43, No. 5, 28.01.2002, p. 847-850.

Research output: Contribution to journal › Article

Nagai, H, Matsumura, S & Toshima, K 2002, 'Environmentally benign and stereoselective formation of β-O-glycosidic linkages using benzyl-protected glucopyranosyl phosphite and montmorillonite K-10', Tetrahedron Letters, vol. 43, no. 5, pp. 847-850. https://doi.org/10.1016/S0040-4039(01)02252-3
Nagai H, Matsumura S, Toshima K. Environmentally benign and stereoselective formation of β-O-glycosidic linkages using benzyl-protected glucopyranosyl phosphite and montmorillonite K-10. Tetrahedron Letters. 2002 Jan 28;43(5):847-850. https://doi.org/10.1016/S0040-4039(01)02252-3
Nagai, Hideyuki ; Matsumura, Shuichi ; Toshima, Kazunobu. / Environmentally benign and stereoselective formation of β-O-glycosidic linkages using benzyl-protected glucopyranosyl phosphite and montmorillonite K-10. In: Tetrahedron Letters. 2002 ; Vol. 43, No. 5. pp. 847-850.
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