Enzymatic synthesis and chemical recycling of poly(carbonate-urethane)

Yasuyuki Soeda, Kazunobu Toshima, Shuichi Matsumura

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

Novel enzymatically recyclable poly(carbonate-urethane) consisting of a diurethane moiety as a hard segment and a carbonate linkage as an enzymatically cleavable unit was prepared by the polycondensation of biodegradable diurethanediol and diethyl carbonate using lipase. The produced poly(carbonate-urethane) was readily transformed by lipase into the corresponding cyclic oligomers which were more easily repolymerized by lipase to produce a higher molecular weight poly(carbonate-urethane) than that of the parent poly(carbonate-urethane).

Original languageEnglish
Pages (from-to)721-728
Number of pages8
JournalMacromolecular Bioscience
Volume4
Issue number8
DOIs
Publication statusPublished - 2004 Aug 9

Keywords

  • Chemical recycling
  • Enzymes
  • Lipase
  • Polycarbonates
  • Polyurethanes

ASJC Scopus subject areas

  • Biotechnology
  • Bioengineering
  • Biomaterials
  • Polymers and Plastics
  • Materials Chemistry

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