Enzyme-catalyzed chemical recycling of bio-based polymers

Satoko Sugihara, Asato Kondo, Kazunobu Toshima, Shuichi Matsumura

Research output: Contribution to conferencePaper

Abstract

Chemical recycling of bio-based polymers such as poly(butylene adipate) and poly(butylene succinate), were studied using an enzyme. Chemically recyclable bio-based polymers were prepared via the ring-opening polymerization of cyclic oligomers which were produced by the condensation of diols and dicarboxylates by lipase in a toluene solution. The cyclic oligomer was readily polymerized by the same lipase in more concentrated solution to produce a high-molecular weight polyester. The produced polyester was readily degraded by lipase to produce cyclic oligomers as the chemical recycling. In this report, the effect of ring-size of cyclic oligomer was studied with respect to the repolymerizability.

Original languageEnglish
Pages5624-5625
Number of pages2
Publication statusPublished - 2006 Dec 1
Event55th Society of Polymer Science Japan Symposium on Macromolecules - Toyama, Japan
Duration: 2006 Sep 202006 Sep 22

Other

Other55th Society of Polymer Science Japan Symposium on Macromolecules
CountryJapan
CityToyama
Period06/9/2006/9/22

Keywords

  • Bio-based polymer
  • Chemical recycling
  • Cyclic oligomer
  • Enzyme

ASJC Scopus subject areas

  • Engineering(all)

Fingerprint Dive into the research topics of 'Enzyme-catalyzed chemical recycling of bio-based polymers'. Together they form a unique fingerprint.

  • Cite this

    Sugihara, S., Kondo, A., Toshima, K., & Matsumura, S. (2006). Enzyme-catalyzed chemical recycling of bio-based polymers. 5624-5625. Paper presented at 55th Society of Polymer Science Japan Symposium on Macromolecules, Toyama, Japan.