EQCM measurement of Sn(II)/Sn reaction in 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)amide room-temperature Ionic liquid

Nobuyuki Serizawa; Naoki Tachikawa; Yasushi Katayama; Takashi Miura

doi:10.5796/electrochemistry.77.630

EQCM measurement of Sn(II)/Sn reaction in 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)amide room-temperature Ionic liquid

Nobuyuki Serizawa, Naoki Tachikawa, Yasushi Katayama, Takashi Miura

Department of Applied Chemistry

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

EQCM (Electrochemical Quartz Crystal Microbalance) measurement during Sn(II)/Sn electrode reaction in a roomtemperature ionic liquid was conducted using an impedance method EQCM, which can measure the resonance resistance and frequency simultaneously. The mass increased during Sn deposition and decreased during Sn dissolution. The viscosity and density of the electrolyte near the electrode, η_Lρ_L, can be estimated by monitoring the resonance resistance. The change of the η_Lρ_L value during Sn(II)/Sn electrode reaction could be accounted for by the concentration profile of Sn(II) near the electrode.

Original language	English
Pages (from-to)	630-632
Number of pages	3
Journal	Electrochemistry
Volume	77
Issue number	8
DOIs	https://doi.org/10.5796/electrochemistry.77.630
Publication status	Published - 2009 Aug

Keywords

Deposition
EQCM
Ionic liquid

ASJC Scopus subject areas

Electrochemistry

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10.5796/electrochemistry.77.630

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abstract = "EQCM (Electrochemical Quartz Crystal Microbalance) measurement during Sn(II)/Sn electrode reaction in a roomtemperature ionic liquid was conducted using an impedance method EQCM, which can measure the resonance resistance and frequency simultaneously. The mass increased during Sn deposition and decreased during Sn dissolution. The viscosity and density of the electrolyte near the electrode, ηLρL, can be estimated by monitoring the resonance resistance. The change of the ηLρL value during Sn(II)/Sn electrode reaction could be accounted for by the concentration profile of Sn(II) near the electrode.",

keywords = "Deposition, EQCM, Ionic liquid",

author = "Nobuyuki Serizawa and Naoki Tachikawa and Yasushi Katayama and Takashi Miura",

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T1 - EQCM measurement of Sn(II)/Sn reaction in 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)amide room-temperature Ionic liquid

AU - Serizawa, Nobuyuki

AU - Tachikawa, Naoki

AU - Katayama, Yasushi

AU - Miura, Takashi

PY - 2009/8

Y1 - 2009/8

N2 - EQCM (Electrochemical Quartz Crystal Microbalance) measurement during Sn(II)/Sn electrode reaction in a roomtemperature ionic liquid was conducted using an impedance method EQCM, which can measure the resonance resistance and frequency simultaneously. The mass increased during Sn deposition and decreased during Sn dissolution. The viscosity and density of the electrolyte near the electrode, ηLρL, can be estimated by monitoring the resonance resistance. The change of the ηLρL value during Sn(II)/Sn electrode reaction could be accounted for by the concentration profile of Sn(II) near the electrode.

AB - EQCM (Electrochemical Quartz Crystal Microbalance) measurement during Sn(II)/Sn electrode reaction in a roomtemperature ionic liquid was conducted using an impedance method EQCM, which can measure the resonance resistance and frequency simultaneously. The mass increased during Sn deposition and decreased during Sn dissolution. The viscosity and density of the electrolyte near the electrode, ηLρL, can be estimated by monitoring the resonance resistance. The change of the ηLρL value during Sn(II)/Sn electrode reaction could be accounted for by the concentration profile of Sn(II) near the electrode.

KW - Deposition

KW - EQCM

KW - Ionic liquid

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JO - Electrochemistry

JF - Electrochemistry

SN - 1344-3542

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EQCM measurement of Sn(II)/Sn reaction in 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)amide room-temperature Ionic liquid

Abstract

Keywords

ASJC Scopus subject areas

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