Equilibrium between Fe(iv) porphyrin and Fe(iii) porphyrin radical cation: New insight into the electronic structure of high-valent iron porphyrin complexes

Akira Ikezaki, Masashi Takahashi, Mikio Nakamura

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

UV-Vis, NMR, and Mössbauer studies have revealed that [Fe(TMP)(N 3)2], showing the Mössbauer parameters quite similar to those of the ferryl species of MauG, CytP450BM3, Cyt P450 CAM, and CPO, exists as equilibrium mixtures of Fe(iv) porphyrin and Fe(iii) porphyrin radical cation.

Original languageEnglish
Pages (from-to)3098-3100
Number of pages3
JournalChemical Communications
Volume49
Issue number30
DOIs
Publication statusPublished - 2013 Apr 18
Externally publishedYes

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Porphyrins
Electronic structure
Cations
Iron
Positive ions
Thymidine Monophosphate
Computer aided manufacturing
Nuclear magnetic resonance

ASJC Scopus subject areas

  • Metals and Alloys
  • Materials Chemistry
  • Surfaces, Coatings and Films
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Catalysis
  • Chemistry(all)

Cite this

Equilibrium between Fe(iv) porphyrin and Fe(iii) porphyrin radical cation : New insight into the electronic structure of high-valent iron porphyrin complexes. / Ikezaki, Akira; Takahashi, Masashi; Nakamura, Mikio.

In: Chemical Communications, Vol. 49, No. 30, 18.04.2013, p. 3098-3100.

Research output: Contribution to journalArticle

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