ESR study and deuteration effect on the magnetic property of hydrogen-bonded benzimidazole nitronyl nitroxide

Hideaki Nagashima, Munetoshi Irisawa, Naoki Yoshioka, Hidenari Inoue

Research output: Contribution to journalConference article

14 Citations (Scopus)

Abstract

A solution ESR spectral investigation on 2-(benzimidazol-2-yl)-4,4,5,5- tetramethyl-1H-imidazoline-1-oxyl-3-oxide (= BIm-NN) and a magnetic susceptibility measurement of its -(N)H deuterated sample (BIm-NN-d1) were carried out. A moderate amount of spin density was observed in benzimidazole ring bearing a hydrogen-bonding site. There was no appreciable difference in the temperature dependence of magnetic susceptibility between BIm-NN and BIm-NN-d1.

Original languageEnglish
Pages (from-to)371-376
Number of pages6
JournalMolecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
Volume376
DOIs
Publication statusPublished - 2002
EventProceedings of the Interdisciplinary Symposium on Multifunctionality of Inorganic , Organic, and Their Hybrid Solids - Honolulu, HI, United States
Duration: 2000 Dec 152000 Dec 18

Keywords

  • Benzimidazole
  • Hydrogen bond
  • Magneto-structural relationship
  • Nitronyl nitroxide

ASJC Scopus subject areas

  • Condensed Matter Physics

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