Ethylene oligomerization catalyzed with dichlorobis-(β-diketonato)zirconium/organoaluminium chloride systems

Kunihiro Oouchi; Makoto Mitani; Michiya Hayakawa; Tohru Yamada; Teruaki Mukaiyama

doi:10.1002/macp.1996.021970430

Ethylene oligomerization catalyzed with dichlorobis-(β-diketonato)zirconium/organoaluminium chloride systems

Kunihiro Oouchi, Makoto Mitani, Michiya Hayakawa, Tohru Yamada, Teruaki Mukaiyama

Research output: Contribution to journal › Article › peer-review

47 Citations (Scopus)

Abstract

The combination of a dichlorobis(β-diketonato)zirconium compound 1 and dimethylaluminium chloride was found to be an active catalyst for the oligomerization of ethylene to produce linear C₄-C₂₂ α-olefins. The catalytic activity and the product distribution of the resulting oligomers was influenced by the structure of the β-diketonato ligands, which affect the electron density at the zirconium center.

Original language	English
Pages (from-to)	1545-1551
Number of pages	7
Journal	Macromolecular Chemistry and Physics
Volume	197
Issue number	4
DOIs	https://doi.org/10.1002/macp.1996.021970430
Publication status	Published - 1996 Apr
Externally published	Yes

ASJC Scopus subject areas

Condensed Matter Physics
Physical and Theoretical Chemistry
Polymers and Plastics
Organic Chemistry
Materials Chemistry

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10.1002/macp.1996.021970430

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abstract = "The combination of a dichlorobis(β-diketonato)zirconium compound 1 and dimethylaluminium chloride was found to be an active catalyst for the oligomerization of ethylene to produce linear C4-C22 α-olefins. The catalytic activity and the product distribution of the resulting oligomers was influenced by the structure of the β-diketonato ligands, which affect the electron density at the zirconium center.",

author = "Kunihiro Oouchi and Makoto Mitani and Michiya Hayakawa and Tohru Yamada and Teruaki Mukaiyama",

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AU - Oouchi, Kunihiro

AU - Mitani, Makoto

AU - Hayakawa, Michiya

AU - Yamada, Tohru

AU - Mukaiyama, Teruaki

PY - 1996/4

Y1 - 1996/4

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AB - The combination of a dichlorobis(β-diketonato)zirconium compound 1 and dimethylaluminium chloride was found to be an active catalyst for the oligomerization of ethylene to produce linear C4-C22 α-olefins. The catalytic activity and the product distribution of the resulting oligomers was influenced by the structure of the β-diketonato ligands, which affect the electron density at the zirconium center.

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Ethylene oligomerization catalyzed with dichlorobis-(β-diketonato)zirconium/organoaluminium chloride systems

Abstract

ASJC Scopus subject areas

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