Evidence of the chemical uniaxial strain effect on electrical conductivity in the spin-crossover conducting molecular system

[FeIII(qnal) 2][Pd(dmit)2]5·acetone

Kazuyuki Takahashi, Heng Bo Cui, Yoshinori Okano, Hayao Kobayashi, Hatsumi Mori, Hiroyuki Tajima, Yasuaki Einaga, Osamu Sato

Research output: Contribution to journalArticle

109 Citations (Scopus)

Abstract

A novel spin-crossover molecular conductor, [Fe(qnal)2][Pd(dmit)2]5·acetone, was prepared and characterized. The crystal structural analyses of both the low- and high-temperature phases revealed that the supramolecular π-π interactions between the spin-crossover Fe(qnal)2 cations as well as the cation contraction play an important role in the uniaxial lattice deformation which will modulate the electrical conductivity of the conducting Pd(dmit)2 layer.

Original languageEnglish
Pages (from-to)6688-6689
Number of pages2
JournalJournal of the American Chemical Society
Volume130
Issue number21
DOIs
Publication statusPublished - 2008 May 28

Fingerprint

Electric Conductivity
Cations
Positive ions
Temperature
Crystals

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Evidence of the chemical uniaxial strain effect on electrical conductivity in the spin-crossover conducting molecular system : [FeIII(qnal) 2][Pd(dmit)2]5·acetone. / Takahashi, Kazuyuki; Cui, Heng Bo; Okano, Yoshinori; Kobayashi, Hayao; Mori, Hatsumi; Tajima, Hiroyuki; Einaga, Yasuaki; Sato, Osamu.

In: Journal of the American Chemical Society, Vol. 130, No. 21, 28.05.2008, p. 6688-6689.

Research output: Contribution to journalArticle

Takahashi, Kazuyuki ; Cui, Heng Bo ; Okano, Yoshinori ; Kobayashi, Hayao ; Mori, Hatsumi ; Tajima, Hiroyuki ; Einaga, Yasuaki ; Sato, Osamu. / Evidence of the chemical uniaxial strain effect on electrical conductivity in the spin-crossover conducting molecular system : [FeIII(qnal) 2][Pd(dmit)2]5·acetone. In: Journal of the American Chemical Society. 2008 ; Vol. 130, No. 21. pp. 6688-6689.
@article{180bbccd55ae44aca9a82439d74c4bbb,
title = "Evidence of the chemical uniaxial strain effect on electrical conductivity in the spin-crossover conducting molecular system: [FeIII(qnal) 2][Pd(dmit)2]5·acetone",
abstract = "A novel spin-crossover molecular conductor, [Fe(qnal)2][Pd(dmit)2]5·acetone, was prepared and characterized. The crystal structural analyses of both the low- and high-temperature phases revealed that the supramolecular π-π interactions between the spin-crossover Fe(qnal)2 cations as well as the cation contraction play an important role in the uniaxial lattice deformation which will modulate the electrical conductivity of the conducting Pd(dmit)2 layer.",
author = "Kazuyuki Takahashi and Cui, {Heng Bo} and Yoshinori Okano and Hayao Kobayashi and Hatsumi Mori and Hiroyuki Tajima and Yasuaki Einaga and Osamu Sato",
year = "2008",
month = "5",
day = "28",
doi = "10.1021/ja801585r",
language = "English",
volume = "130",
pages = "6688--6689",
journal = "Journal of the American Chemical Society",
issn = "0002-7863",
publisher = "American Chemical Society",
number = "21",

}

TY - JOUR

T1 - Evidence of the chemical uniaxial strain effect on electrical conductivity in the spin-crossover conducting molecular system

T2 - [FeIII(qnal) 2][Pd(dmit)2]5·acetone

AU - Takahashi, Kazuyuki

AU - Cui, Heng Bo

AU - Okano, Yoshinori

AU - Kobayashi, Hayao

AU - Mori, Hatsumi

AU - Tajima, Hiroyuki

AU - Einaga, Yasuaki

AU - Sato, Osamu

PY - 2008/5/28

Y1 - 2008/5/28

N2 - A novel spin-crossover molecular conductor, [Fe(qnal)2][Pd(dmit)2]5·acetone, was prepared and characterized. The crystal structural analyses of both the low- and high-temperature phases revealed that the supramolecular π-π interactions between the spin-crossover Fe(qnal)2 cations as well as the cation contraction play an important role in the uniaxial lattice deformation which will modulate the electrical conductivity of the conducting Pd(dmit)2 layer.

AB - A novel spin-crossover molecular conductor, [Fe(qnal)2][Pd(dmit)2]5·acetone, was prepared and characterized. The crystal structural analyses of both the low- and high-temperature phases revealed that the supramolecular π-π interactions between the spin-crossover Fe(qnal)2 cations as well as the cation contraction play an important role in the uniaxial lattice deformation which will modulate the electrical conductivity of the conducting Pd(dmit)2 layer.

UR - http://www.scopus.com/inward/record.url?scp=44349152345&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=44349152345&partnerID=8YFLogxK

U2 - 10.1021/ja801585r

DO - 10.1021/ja801585r

M3 - Article

VL - 130

SP - 6688

EP - 6689

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

SN - 0002-7863

IS - 21

ER -