Evidence of the chemical uniaxial strain effect on electrical conductivity in the spin-crossover conducting molecular system: [FeIII(qnal) 2][Pd(dmit)2]5·acetone

Kazuyuki Takahashi, Heng Bo Cui, Yoshinori Okano, Hayao Kobayashi, Hatsumi Mori, Hiroyuki Tajima, Yasuaki Einaga, Osamu Sato

Research output: Contribution to journalArticlepeer-review

120 Citations (Scopus)

Abstract

A novel spin-crossover molecular conductor, [Fe(qnal)2][Pd(dmit)2]5·acetone, was prepared and characterized. The crystal structural analyses of both the low- and high-temperature phases revealed that the supramolecular π-π interactions between the spin-crossover Fe(qnal)2 cations as well as the cation contraction play an important role in the uniaxial lattice deformation which will modulate the electrical conductivity of the conducting Pd(dmit)2 layer.

Original languageEnglish
Pages (from-to)6688-6689
Number of pages2
JournalJournal of the American Chemical Society
Volume130
Issue number21
DOIs
Publication statusPublished - 2008 May 28

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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