Evidence of the chemical uniaxial strain effect on electrical conductivity in the spin-crossover conducting molecular system: [FeIII(qnal) 2][Pd(dmit)2]5·acetone

Kazuyuki Takahashi, Heng Bo Cui, Yoshinori Okano, Hayao Kobayashi, Hatsumi Mori, Hiroyuki Tajima, Yasuaki Einaga, Osamu Sato

Research output: Contribution to journal › Article

114 Citations (Scopus)

Abstract

A novel spin-crossover molecular conductor, [Fe(qnal)2][Pd(dmit)2]5·acetone, was prepared and characterized. The crystal structural analyses of both the low- and high-temperature phases revealed that the supramolecular π-π interactions between the spin-crossover Fe(qnal)2 cations as well as the cation contraction play an important role in the uniaxial lattice deformation which will modulate the electrical conductivity of the conducting Pd(dmit)2 layer.

Original languageEnglish
Pages (from-to)6688-6689
Number of pages2
JournalJournal of the American Chemical Society
Volume130
Issue number21
DOIs
Publication statusPublished - 2008 May 28

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Electric Conductivity
Cations
Positive ions
Temperature
Crystals

ASJC Scopus subject areas

  • Chemistry(all)

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Evidence of the chemical uniaxial strain effect on electrical conductivity in the spin-crossover conducting molecular system : [FeIII(qnal) 2][Pd(dmit)2]5·acetone. / Takahashi, Kazuyuki; Cui, Heng Bo; Okano, Yoshinori; Kobayashi, Hayao; Mori, Hatsumi; Tajima, Hiroyuki; Einaga, Yasuaki; Sato, Osamu.

In: Journal of the American Chemical Society, Vol. 130, No. 21, 28.05.2008, p. 6688-6689.

Research output: Contribution to journal › Article

Takahashi, K, Cui, HB, Okano, Y, Kobayashi, H, Mori, H, Tajima, H, Einaga, Y & Sato, O 2008, 'Evidence of the chemical uniaxial strain effect on electrical conductivity in the spin-crossover conducting molecular system: [FeIII(qnal) 2][Pd(dmit)2]5·acetone', Journal of the American Chemical Society, vol. 130, no. 21, pp. 6688-6689. https://doi.org/10.1021/ja801585r
Takahashi K, Cui HB, Okano Y, Kobayashi H, Mori H, Tajima H et al. Evidence of the chemical uniaxial strain effect on electrical conductivity in the spin-crossover conducting molecular system: [FeIII(qnal) 2][Pd(dmit)2]5·acetone. Journal of the American Chemical Society. 2008 May 28;130(21):6688-6689. https://doi.org/10.1021/ja801585r
Takahashi, Kazuyuki ; Cui, Heng Bo ; Okano, Yoshinori ; Kobayashi, Hayao ; Mori, Hatsumi ; Tajima, Hiroyuki ; Einaga, Yasuaki ; Sato, Osamu. / Evidence of the chemical uniaxial strain effect on electrical conductivity in the spin-crossover conducting molecular system : [FeIII(qnal) 2][Pd(dmit)2]5·acetone. In: Journal of the American Chemical Society. 2008 ; Vol. 130, No. 21. pp. 6688-6689.
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