Excited state charge transfer and dissociation of Mg+-CH3I complex

Fuminori Misaizu, Ari Furuya, Hironori Tsunoyama, Koichi Ohno

Research output: Chapter in Book/Report/Conference proceedingChapter

Abstract

Photodissociation of Mg+-CH3l has been studied in the UV region using a reflectron time-of-flight mass spectrometer. Three bands were observed in a dissociation spectrum peaking at about 27200, 29600, and 38100 cm-1, which were assigned to the bands originating from 2P←2S transition of Mg+. Five kinds of ions, CH3 +, Mg+, I+, CH3I+, and Mgl+, were observed as fragment ions. Dissociation processes were discussed from the consideration of potential energy curves including charge transfer states obtained by CIS calculation.

Original languageEnglish
Title of host publicationClusters and Nano-Assemblies: Physical and Biological Systems: Richmond, Virginia, U.S.A., 10-13 November, 2003
PublisherWorld Scientific Publishing Co.
Pages89-95
Number of pages7
ISBN (Print)9789812701879, 9812563318, 9789812563316
DOIs
Publication statusPublished - 2005 Jan 1
Externally publishedYes

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ASJC Scopus subject areas

  • Engineering(all)

Cite this

Misaizu, F., Furuya, A., Tsunoyama, H., & Ohno, K. (2005). Excited state charge transfer and dissociation of Mg+-CH3I complex. In Clusters and Nano-Assemblies: Physical and Biological Systems: Richmond, Virginia, U.S.A., 10-13 November, 2003 (pp. 89-95). World Scientific Publishing Co.. https://doi.org/10.1142/9789812701879_0012