exo-[(RS,SR)-N,N′-Bis(salicylidene)-2,3-butanediaminato] oxovanadium(IV)

Gakuse Hoshina, Masanobu Tsuchimoto, Shigeru Ohba

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

The thermally more stable isomer of the title complex, {2,2′-[(RS,SR)-2,3-butanediylbis (nitrilomethylidene)]diphenolato-O,N,N′,O′}oxovanadium(IV), [VO(C18H18N2O2)] or [VO(sal-meso-bn)] [H2sal-meso-bn is (RS,SR)-N,N′-bis(salicylidene)-2,3-butanediamine], in the solid state, has been determined to be the exo isomer. The two methyl groups of the central diamine moiety in the Schiff base ligand are on the same side of the N2Ooxo plane of the VN2O3 square pyramid as the oxo ligand. The V=O distance is 1.595 (2) Å, and the V atom is displaced by 0.50 (1) Å toward the oxo ligand from the N2O2 basal plane. There is an intermolecular V⋯Osalicyl close contact of 2.972 (2) Å, which is trans to the V=O bond.

Original languageEnglish
Pages (from-to)1082-1084
Number of pages3
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume55
Issue number7
Publication statusPublished - 1999 Jul 15

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Ligands
Isomers
ligands
isomers
Diamines
Schiff Bases
diamines
pyramids
imines
solid state
Atoms
atoms
oxovanadium IV

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Structural Biology

Cite this

exo-[(RS,SR)-N,N′-Bis(salicylidene)-2,3-butanediaminato] oxovanadium(IV). / Hoshina, Gakuse; Tsuchimoto, Masanobu; Ohba, Shigeru.

In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 55, No. 7, 15.07.1999, p. 1082-1084.

Research output: Contribution to journalArticle

Hoshina, Gakuse ; Tsuchimoto, Masanobu ; Ohba, Shigeru. / exo-[(RS,SR)-N,N′-Bis(salicylidene)-2,3-butanediaminato] oxovanadium(IV). In: Acta Crystallographica Section C: Crystal Structure Communications. 1999 ; Vol. 55, No. 7. pp. 1082-1084.
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