Facile syntheses of (+)-gabosines A, D, and e

Tony Kung Ming Shing, Hau M. Cheng

Research output: Contribution to journalArticle

22 Citations (Scopus)

Abstract

(+)-Gabosines A (12), D (4), and E (5), which share the same trihydroxycyclohexenone skeleton, were synthesized from enone 11 as the common intermediate. The key building block 11 was accessed by an intramolecular aldol cyclization of a diketone derived from d-glucose (8).

Original languageEnglish
Pages (from-to)5098-5102
Number of pages5
JournalOrganic and Biomolecular Chemistry
Volume7
Issue number24
DOIs
Publication statusPublished - 2009 Dec 29
Externally publishedYes

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Cyclization
musculoskeletal system
Skeleton
glucose
Glucose
synthesis
gabosine D
gabosine A
3-hydroxybutanal

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

Cite this

Facile syntheses of (+)-gabosines A, D, and e. / Shing, Tony Kung Ming; Cheng, Hau M.

In: Organic and Biomolecular Chemistry, Vol. 7, No. 24, 29.12.2009, p. 5098-5102.

Research output: Contribution to journalArticle

Shing, Tony Kung Ming ; Cheng, Hau M. / Facile syntheses of (+)-gabosines A, D, and e. In: Organic and Biomolecular Chemistry. 2009 ; Vol. 7, No. 24. pp. 5098-5102.
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