Formation and characterization of a six-coordinate iron(iii) complex with the most ruffled porphyrin ring

Akira Ikezaki, Mikio Nakamura

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

The six-coordinate iron(iii) porphyrin complex, [Fe(TiPrP)(2- MeBzIm)2]+, having the most ruffled porphyrin ring shows some unusual properties; the complex adopts the pure (dxz, d yz)4(dxy)1 ground state below 200 K in spite of the coordination of an imidazole ligand and exhibits the rare spin transition to the (dxz, dyz)3(d xy)1(dz2)1 state at higher temperature.

Original languageEnglish
Pages (from-to)3455-3458
Number of pages4
JournalDalton Transactions
Volume40
Issue number14
DOIs
Publication statusPublished - 2011

ASJC Scopus subject areas

  • Inorganic Chemistry

Fingerprint Dive into the research topics of 'Formation and characterization of a six-coordinate iron(iii) complex with the most ruffled porphyrin ring'. Together they form a unique fingerprint.

  • Cite this