Formation and characterization of a six-coordinate iron(iii) complex with the most ruffled porphyrin ring

Akira Ikezaki, Mikio Nakamura

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

The six-coordinate iron(iii) porphyrin complex, [Fe(TiPrP)(2- MeBzIm)2]+, having the most ruffled porphyrin ring shows some unusual properties; the complex adopts the pure (dxz, d yz)4(dxy)1 ground state below 200 K in spite of the coordination of an imidazole ligand and exhibits the rare spin transition to the (dxz, dyz)3(d xy)1(dz2)1 state at higher temperature.

Original languageEnglish
Pages (from-to)3455-3458
Number of pages4
JournalDalton Transactions
Volume40
Issue number14
DOIs
Publication statusPublished - 2011
Externally publishedYes

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Porphyrins
Iron
Ground state
Ligands
Temperature
imidazole

ASJC Scopus subject areas

  • Inorganic Chemistry

Cite this

Formation and characterization of a six-coordinate iron(iii) complex with the most ruffled porphyrin ring. / Ikezaki, Akira; Nakamura, Mikio.

In: Dalton Transactions, Vol. 40, No. 14, 2011, p. 3455-3458.

Research output: Contribution to journalArticle

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