Formation of α-Monosubstituted propargylamines from terminal alkynes and secondary amines using a (PNO)Rh/Cu Tandem catalyst system

Research output: Contribution to journalReview article

4 Citations (Scopus)

Abstract

A novel (PNO)Rh/CuBr (PNO: phosphine-quinolinolate) tandem catalyst system was developed for facile synthesis of α-monosubstituted propargylamines from aliphatic terminal al-kynes and secondary amines. Various terminal alkynes and amines were applicable to this reaction and the corresponding propargylamines were obtained in good yields.

Original languageEnglish
Pages (from-to)1620-1623
Number of pages4
JournalChemistry Letters
Volume46
Issue number11
DOIs
Publication statusPublished - 2017

Fingerprint

phosphine
Alkynes
Amines
Catalysts
propargylamine

Keywords

  • Propargylamines
  • Rhodium catalysts
  • Terminal alkynes

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

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title = "Formation of α-Monosubstituted propargylamines from terminal alkynes and secondary amines using a (PNO)Rh/Cu Tandem catalyst system",
abstract = "A novel (PNO)Rh/CuBr (PNO: phosphine-quinolinolate) tandem catalyst system was developed for facile synthesis of α-monosubstituted propargylamines from aliphatic terminal al-kynes and secondary amines. Various terminal alkynes and amines were applicable to this reaction and the corresponding propargylamines were obtained in good yields.",
keywords = "Propargylamines, Rhodium catalysts, Terminal alkynes",
author = "Shotaro Takano and Takuya Kochi and Fumitoshi Kakiuchi",
year = "2017",
doi = "10.1246/cl.170754",
language = "English",
volume = "46",
pages = "1620--1623",
journal = "Chemistry Letters",
issn = "0366-7022",
publisher = "Chemical Society of Japan",
number = "11",

}

TY - JOUR

T1 - Formation of α-Monosubstituted propargylamines from terminal alkynes and secondary amines using a (PNO)Rh/Cu Tandem catalyst system

AU - Takano, Shotaro

AU - Kochi, Takuya

AU - Kakiuchi, Fumitoshi

PY - 2017

Y1 - 2017

N2 - A novel (PNO)Rh/CuBr (PNO: phosphine-quinolinolate) tandem catalyst system was developed for facile synthesis of α-monosubstituted propargylamines from aliphatic terminal al-kynes and secondary amines. Various terminal alkynes and amines were applicable to this reaction and the corresponding propargylamines were obtained in good yields.

AB - A novel (PNO)Rh/CuBr (PNO: phosphine-quinolinolate) tandem catalyst system was developed for facile synthesis of α-monosubstituted propargylamines from aliphatic terminal al-kynes and secondary amines. Various terminal alkynes and amines were applicable to this reaction and the corresponding propargylamines were obtained in good yields.

KW - Propargylamines

KW - Rhodium catalysts

KW - Terminal alkynes

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U2 - 10.1246/cl.170754

DO - 10.1246/cl.170754

M3 - Review article

AN - SCOPUS:85032514650

VL - 46

SP - 1620

EP - 1623

JO - Chemistry Letters

JF - Chemistry Letters

SN - 0366-7022

IS - 11

ER -