Formation of α-Monosubstituted propargylamines from terminal alkynes and secondary amines using a (PNO)Rh/Cu Tandem catalyst system

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Abstract

A novel (PNO)Rh/CuBr (PNO: phosphine-quinolinolate) tandem catalyst system was developed for facile synthesis of α-monosubstituted propargylamines from aliphatic terminal al-kynes and secondary amines. Various terminal alkynes and amines were applicable to this reaction and the corresponding propargylamines were obtained in good yields.

Original languageEnglish
Pages (from-to)1620-1623
Number of pages4
JournalChemistry Letters
Volume46
Issue number11
DOIs
Publication statusPublished - 2017

Keywords

  • Propargylamines
  • Rhodium catalysts
  • Terminal alkynes

ASJC Scopus subject areas

  • Chemistry(all)

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