Formation of cobalt-C60 clusters: Tricapped Co(C60)3 unit

Tsuyoshi Kurikawa, Satoshi Nagao, Ken Miyajima, Atsushi Nakajima, Koji Kaya

Research output: Contribution to journalArticle

40 Citations (Scopus)

Abstract

Cobalt (Co)-C60 mixed clusters were produced by the combination of laser vaporization and molecular beam methods. Cationic Con(C60)m+ clusters were produced predominantly with the compositions (n, m) = (0-1, 1), (1, 2), (1, 3), (2-4, 4), and (5, 5). Both mass spectrometry and a chemical probe method have revealed that compositions of (1, 3) and (4, 4) correspond to a tricapped planar structure and a tricapped trigonal pyramid structure, respectively, in which each Co atom is surrounded by three C60.

Original languageEnglish
Pages (from-to)1743-1747
Number of pages5
JournalJournal of Physical Chemistry A
Volume102
Issue number10
Publication statusPublished - 1998 Mar 5

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Cobalt
cobalt
Molecular beams
planar structures
pyramids
Chemical analysis
Vaporization
molecular beams
Mass spectrometry
mass spectroscopy
Atoms
Lasers
lasers
atoms

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

Cite this

Kurikawa, T., Nagao, S., Miyajima, K., Nakajima, A., & Kaya, K. (1998). Formation of cobalt-C60 clusters: Tricapped Co(C60)3 unit. Journal of Physical Chemistry A, 102(10), 1743-1747.

Formation of cobalt-C60 clusters : Tricapped Co(C60)3 unit. / Kurikawa, Tsuyoshi; Nagao, Satoshi; Miyajima, Ken; Nakajima, Atsushi; Kaya, Koji.

In: Journal of Physical Chemistry A, Vol. 102, No. 10, 05.03.1998, p. 1743-1747.

Research output: Contribution to journalArticle

Kurikawa, T, Nagao, S, Miyajima, K, Nakajima, A & Kaya, K 1998, 'Formation of cobalt-C60 clusters: Tricapped Co(C60)3 unit', Journal of Physical Chemistry A, vol. 102, no. 10, pp. 1743-1747.
Kurikawa T, Nagao S, Miyajima K, Nakajima A, Kaya K. Formation of cobalt-C60 clusters: Tricapped Co(C60)3 unit. Journal of Physical Chemistry A. 1998 Mar 5;102(10):1743-1747.
Kurikawa, Tsuyoshi ; Nagao, Satoshi ; Miyajima, Ken ; Nakajima, Atsushi ; Kaya, Koji. / Formation of cobalt-C60 clusters : Tricapped Co(C60)3 unit. In: Journal of Physical Chemistry A. 1998 ; Vol. 102, No. 10. pp. 1743-1747.
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