Formation of hollow silica spheres with ordered mesoporous structure by treatment with dimethyl carbonate for selective decomposition of mesoporous silica core

Masaki Okamoto, Huimin Huang

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

Hollow silica spheres containing ordered mesopores with radial orientation were synthesized from core-shell structured mesoporous silica spheres with pure silica core and propyl group-grafted silica shell. The silica core was selectively impregnated with sodium acetate owing to the hydrophilicity of the core. Sodium acetate acted as a catalyst for silica decomposition with dimethyl carbonate (DMC), and after impregnation, treatment with DMC was performed to remove the core by the reaction of silica with DMC. The obtained hollow spheres contain ordered mesopores with radial orientation and are mono-disperse. The final shell thickness could be controlled by changing the shell thickness of the initial core-shell spheres, as well as by modifying the degree of decomposition of the shell. 9-Phenylanthracene encapsulated in the hollow spheres was gradually released through the mesopores as vapor into an air stream by diffusion limitation.

Original languageEnglish
Pages (from-to)102-109
Number of pages8
JournalMicroporous and Mesoporous Materials
Volume163
DOIs
Publication statusPublished - 2012 Nov 15
Externally publishedYes

Fingerprint

Silicon Dioxide
Carbonates
hollow
carbonates
Silica
silicon dioxide
Decomposition
decomposition
Sodium Acetate
acetates
Sodium
sodium
Hydrophilicity
methyl carbonate
Impregnation
Vapors
vapors
catalysts
Catalysts
air

Keywords

  • Dimethyl carbonate
  • Hollow sphere
  • Mesoporous silica

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials

Cite this

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title = "Formation of hollow silica spheres with ordered mesoporous structure by treatment with dimethyl carbonate for selective decomposition of mesoporous silica core",
abstract = "Hollow silica spheres containing ordered mesopores with radial orientation were synthesized from core-shell structured mesoporous silica spheres with pure silica core and propyl group-grafted silica shell. The silica core was selectively impregnated with sodium acetate owing to the hydrophilicity of the core. Sodium acetate acted as a catalyst for silica decomposition with dimethyl carbonate (DMC), and after impregnation, treatment with DMC was performed to remove the core by the reaction of silica with DMC. The obtained hollow spheres contain ordered mesopores with radial orientation and are mono-disperse. The final shell thickness could be controlled by changing the shell thickness of the initial core-shell spheres, as well as by modifying the degree of decomposition of the shell. 9-Phenylanthracene encapsulated in the hollow spheres was gradually released through the mesopores as vapor into an air stream by diffusion limitation.",
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author = "Masaki Okamoto and Huimin Huang",
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T1 - Formation of hollow silica spheres with ordered mesoporous structure by treatment with dimethyl carbonate for selective decomposition of mesoporous silica core

AU - Okamoto, Masaki

AU - Huang, Huimin

PY - 2012/11/15

Y1 - 2012/11/15

N2 - Hollow silica spheres containing ordered mesopores with radial orientation were synthesized from core-shell structured mesoporous silica spheres with pure silica core and propyl group-grafted silica shell. The silica core was selectively impregnated with sodium acetate owing to the hydrophilicity of the core. Sodium acetate acted as a catalyst for silica decomposition with dimethyl carbonate (DMC), and after impregnation, treatment with DMC was performed to remove the core by the reaction of silica with DMC. The obtained hollow spheres contain ordered mesopores with radial orientation and are mono-disperse. The final shell thickness could be controlled by changing the shell thickness of the initial core-shell spheres, as well as by modifying the degree of decomposition of the shell. 9-Phenylanthracene encapsulated in the hollow spheres was gradually released through the mesopores as vapor into an air stream by diffusion limitation.

AB - Hollow silica spheres containing ordered mesopores with radial orientation were synthesized from core-shell structured mesoporous silica spheres with pure silica core and propyl group-grafted silica shell. The silica core was selectively impregnated with sodium acetate owing to the hydrophilicity of the core. Sodium acetate acted as a catalyst for silica decomposition with dimethyl carbonate (DMC), and after impregnation, treatment with DMC was performed to remove the core by the reaction of silica with DMC. The obtained hollow spheres contain ordered mesopores with radial orientation and are mono-disperse. The final shell thickness could be controlled by changing the shell thickness of the initial core-shell spheres, as well as by modifying the degree of decomposition of the shell. 9-Phenylanthracene encapsulated in the hollow spheres was gradually released through the mesopores as vapor into an air stream by diffusion limitation.

KW - Dimethyl carbonate

KW - Hollow sphere

KW - Mesoporous silica

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