Formation of the Intermediate-Spin Iron(III) Porphyrin Complexes with (dxz, dyz)3(dxy)1(d z2)1 Electron Configuration

Takanori Sakai, Yoshiki Ohgo, Takahisa Ikeue, Masashi Takahashi, Masuo Takeda, Mikio Nakamura

Research output: Contribution to journalArticlepeer-review

54 Citations (Scopus)

Abstract

On the basis of the difference in meso-13C chemical shifts, we have concluded that the intermediate-spin iron(III) complexes with highly ruffled and highly saddled porphyrins have different electron configurations. While the latter has a conventional (dxy)2(dxz, dyz)2(dz2)1, the former adopts a novel (dxz, dyz)3(dxy)1(dz2)1.

Original languageEnglish
Pages (from-to)13028-13029
Number of pages2
JournalJournal of the American Chemical Society
Volume125
Issue number43
DOIs
Publication statusPublished - 2003 Oct 29

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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