Generation and reaction of an oxiranyl anion derived from α,β-epoxy-γ-butyrolactone

Kouji Kuramochi, Hideyoshi Itaya, Seigo Nagata, Kenichi Takao, Susumu Kobayashi

Research output: Contribution to journalArticle

27 Citations (Scopus)

Abstract

Generation and reaction of an oxiranyl anion on a lactone are described. Aldol-type condensation of epoxylactone and aldehydes was accomplished by a two-step procedure via trimethylsilyl epoxylactone.

Original languageEnglish
Pages (from-to)7367-7370
Number of pages4
JournalTetrahedron Letters
Volume40
Issue number41
DOIs
Publication statusPublished - 1999 Oct 8
Externally publishedYes

Fingerprint

Lactones
Aldehydes
Anions
Condensation
3-hydroxybutanal

Keywords

  • β-Angelica lactone epoxide
  • Epolactaene
  • Fluoride-catalyzed aldol reaction
  • Oxiranyl anion

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

Cite this

Generation and reaction of an oxiranyl anion derived from α,β-epoxy-γ-butyrolactone. / Kuramochi, Kouji; Itaya, Hideyoshi; Nagata, Seigo; Takao, Kenichi; Kobayashi, Susumu.

In: Tetrahedron Letters, Vol. 40, No. 41, 08.10.1999, p. 7367-7370.

Research output: Contribution to journalArticle

Kuramochi, Kouji ; Itaya, Hideyoshi ; Nagata, Seigo ; Takao, Kenichi ; Kobayashi, Susumu. / Generation and reaction of an oxiranyl anion derived from α,β-epoxy-γ-butyrolactone. In: Tetrahedron Letters. 1999 ; Vol. 40, No. 41. pp. 7367-7370.
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AU - Kobayashi, Susumu

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