Glycol Cleavage Reactions

A. W.H. Wong; T. K.M. Shing

doi:10.1016/B978-0-08-097742-3.00731-X

Glycol Cleavage Reactions

A. W.H. Wong, T. K.M. Shing

Research output: Chapter in Book/Report/Conference proceeding › Chapter

4 Citations (Scopus)

Abstract

This chapter reviews the development of reagents used for glycol cleavage oxidation reactions of vicinal diols and related functional groups from 1990 to 2012. The reagents are categorized into metallic and nonmetallic reagents. Among the metallic reagents, those involving lead, manganese, ruthenium, and tin elements are versatile. For nonmetallic reagents, periodinane and related compounds are new contenders for the glycol fission reactions. Periodates are still the most popular reagents for the reaction because of their stability, cost, versatility, and efficiency. The applications of glycol cleavage reactions in organic syntheses are also reviewed.

Original language	English
Title of host publication	Oxidation
Publisher	Elsevier Ltd
Pages	801-817
Number of pages	17
Volume	7
ISBN (Print)	9780080977430
DOIs	https://doi.org/10.1016/B978-0-08-097742-3.00731-X
Publication status	Published - 2014 Feb
Externally published	Yes

Keywords

Glycol cleavage
Oxidative fission
Periodates
Vicinal diols

ASJC Scopus subject areas

Chemical Engineering(all)
Chemistry(all)

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10.1016/B978-0-08-097742-3.00731-X

Cite this

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title = "Glycol Cleavage Reactions",

abstract = "This chapter reviews the development of reagents used for glycol cleavage oxidation reactions of vicinal diols and related functional groups from 1990 to 2012. The reagents are categorized into metallic and nonmetallic reagents. Among the metallic reagents, those involving lead, manganese, ruthenium, and tin elements are versatile. For nonmetallic reagents, periodinane and related compounds are new contenders for the glycol fission reactions. Periodates are still the most popular reagents for the reaction because of their stability, cost, versatility, and efficiency. The applications of glycol cleavage reactions in organic syntheses are also reviewed.",

keywords = "Glycol cleavage, Oxidative fission, Periodates, Vicinal diols",

author = "Wong, {A. W.H.} and Shing, {T. K.M.}",

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AU - Shing, T. K.M.

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AB - This chapter reviews the development of reagents used for glycol cleavage oxidation reactions of vicinal diols and related functional groups from 1990 to 2012. The reagents are categorized into metallic and nonmetallic reagents. Among the metallic reagents, those involving lead, manganese, ruthenium, and tin elements are versatile. For nonmetallic reagents, periodinane and related compounds are new contenders for the glycol fission reactions. Periodates are still the most popular reagents for the reaction because of their stability, cost, versatility, and efficiency. The applications of glycol cleavage reactions in organic syntheses are also reviewed.

KW - Glycol cleavage

KW - Oxidative fission

KW - Periodates

KW - Vicinal diols

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M3 - Chapter

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SN - 9780080977430

VL - 7

SP - 801

EP - 817

BT - Oxidation

PB - Elsevier Ltd

ER -

Glycol Cleavage Reactions

Abstract

Keywords

ASJC Scopus subject areas

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