Abstract
β-Stereoselective mannosylations were conducted using a 1,2-anhydromannose donor and mono-ol acceptors in the presence of a glycosyl-acceptor-derived borinic ester. Reactions proceeded smoothly under mild conditions to provide the corresponding β-mannosides with high stereoselectivity in moderate to high yields. In addition, the present glycosylation method was applied successfully to the total synthesis of acremomannolipin A.
| Original language | English |
|---|---|
| Pages (from-to) | 2288-2291 |
| Number of pages | 4 |
| Journal | Organic Letters |
| Volume | 18 |
| Issue number | 9 |
| DOIs | |
| Publication status | Published - 2016 May 6 |
ASJC Scopus subject areas
- Organic Chemistry
- Physical and Theoretical Chemistry
- Biochemistry
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Tanaka, M., Nashida, J., Takahashi, D., & Toshima, K. (2016). Glycosyl-Acceptor-Derived Borinic Ester-Promoted Direct and β-Stereoselective Mannosylation with a 1,2-Anhydromannose Donor. Organic Letters, 18(9), 2288-2291. https://doi.org/10.1021/acs.orglett.6b00926