Abstract
β-Stereoselective mannosylations were conducted using a 1,2-anhydromannose donor and mono-ol acceptors in the presence of a glycosyl-acceptor-derived borinic ester. Reactions proceeded smoothly under mild conditions to provide the corresponding β-mannosides with high stereoselectivity in moderate to high yields. In addition, the present glycosylation method was applied successfully to the total synthesis of acremomannolipin A.
Original language | English |
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Pages (from-to) | 2288-2291 |
Number of pages | 4 |
Journal | Organic Letters |
Volume | 18 |
Issue number | 9 |
DOIs | |
Publication status | Published - 2016 May 6 |
ASJC Scopus subject areas
- Biochemistry
- Physical and Theoretical Chemistry
- Organic Chemistry