Guest-guest and guest-host interactions in ethanol, propan-1-ol, and propan-2-ol clathrate hydrate forming systems

Keita Yasuda, Ryo Ohmura, Amadeu K. Sum

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

In the present study, Raman spectroscopic measurements were performed using clathrate hydrate samples composed of ethanol, propan-1-ol, or propan-2-ol + deuterated methane + deuterium oxide. The temperature of the samples was stepwise increased from 93 K to 263 K in steps of 10 K or 20 K to decompose the clathrate hydrate samples during the measurements. The Raman spectra of the alcohols + deuterated methane hydrate sample in the C-H symmetric vibration region were similar to that of pure vapor alcohols, which indicates the weak guest alcohol-host water interaction although alcohols are hydrophilic compounds. In the propan-2-ol + deuterated methane + deuterium oxide system, the formation of two compounds having different composition from structure II propan-2-ol + deuterated methane clathrate hydrate was observed.

Original languageEnglish
Pages (from-to)7364-7370
Number of pages7
JournalNew Journal of Chemistry
Volume42
Issue number9
DOIs
Publication statusPublished - 2018 Jan 1

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Methane
Hydrates
Alcohols
Ethanol
Deuterium Oxide
Heavy water
Raman scattering
Vapors
Water
Chemical analysis
Temperature

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Materials Chemistry

Cite this

Guest-guest and guest-host interactions in ethanol, propan-1-ol, and propan-2-ol clathrate hydrate forming systems. / Yasuda, Keita; Ohmura, Ryo; Sum, Amadeu K.

In: New Journal of Chemistry, Vol. 42, No. 9, 01.01.2018, p. 7364-7370.

Research output: Contribution to journalArticle

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