Guest-induced symmetry lowering of an ionic clathrate material for carbon capture

S. Muromachi; K. A. Udachin; K. Shin; S. Alavi; I. L. Moudrakovski; R. Ohmura; J. A. Ripmeester

doi:10.1039/c4cc02111h

Guest-induced symmetry lowering of an ionic clathrate material for carbon capture

S. Muromachi, K. A. Udachin, K. Shin, S. Alavi, I. L. Moudrakovski, R. Ohmura, J. A. Ripmeester

Department of Mechanical Engineering

Research output: Contribution to journal › Article › peer-review

56 Citations (Scopus)

Abstract

We report a new lattice structure of the ionic clathrate hydrate of tetra-n-butylammonium bromide induced by guest CO₂ molecules, which is found to provide high CO₂ storage capacity. The structure was characterized by a set of methods, including single crystal X-ray diffraction, NMR, and MD simulations.

Original language	English
Pages (from-to)	11476-11479
Number of pages	4
Journal	Chemical Communications
Volume	50
Issue number	78
DOIs	https://doi.org/10.1039/c4cc02111h
Publication status	Published - 2014 Sep 4

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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abstract = "We report a new lattice structure of the ionic clathrate hydrate of tetra-n-butylammonium bromide induced by guest CO2 molecules, which is found to provide high CO2 storage capacity. The structure was characterized by a set of methods, including single crystal X-ray diffraction, NMR, and MD simulations.",

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AU - Muromachi, S.

AU - Udachin, K. A.

AU - Shin, K.

AU - Alavi, S.

AU - Moudrakovski, I. L.

AU - Ohmura, R.

AU - Ripmeester, J. A.

PY - 2014/9/4

Y1 - 2014/9/4

N2 - We report a new lattice structure of the ionic clathrate hydrate of tetra-n-butylammonium bromide induced by guest CO2 molecules, which is found to provide high CO2 storage capacity. The structure was characterized by a set of methods, including single crystal X-ray diffraction, NMR, and MD simulations.

AB - We report a new lattice structure of the ionic clathrate hydrate of tetra-n-butylammonium bromide induced by guest CO2 molecules, which is found to provide high CO2 storage capacity. The structure was characterized by a set of methods, including single crystal X-ray diffraction, NMR, and MD simulations.

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Guest-induced symmetry lowering of an ionic clathrate material for carbon capture

Abstract

ASJC Scopus subject areas

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