Guest-induced symmetry lowering of an ionic clathrate material for carbon capture

S. Muromachi, K. A. Udachin, K. Shin, S. Alavi, I. L. Moudrakovski, R. Ohmura, J. A. Ripmeester

Research output: Contribution to journalArticle

50 Citations (Scopus)

Abstract

We report a new lattice structure of the ionic clathrate hydrate of tetra-n-butylammonium bromide induced by guest CO2 molecules, which is found to provide high CO2 storage capacity. The structure was characterized by a set of methods, including single crystal X-ray diffraction, NMR, and MD simulations.

Original languageEnglish
Pages (from-to)11476-11479
Number of pages4
JournalChemical Communications
Volume50
Issue number78
DOIs
Publication statusPublished - 2014 Sep 4

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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  • Cite this

    Muromachi, S., Udachin, K. A., Shin, K., Alavi, S., Moudrakovski, I. L., Ohmura, R., & Ripmeester, J. A. (2014). Guest-induced symmetry lowering of an ionic clathrate material for carbon capture. Chemical Communications, 50(78), 11476-11479. https://doi.org/10.1039/c4cc02111h