Guest-induced symmetry lowering of an ionic clathrate material for carbon capture

S. Muromachi, K. A. Udachin, K. Shin, S. Alavi, I. L. Moudrakovski, Ryo Ohmura, J. A. Ripmeester

Research output: Contribution to journalArticle

43 Citations (Scopus)

Abstract

We report a new lattice structure of the ionic clathrate hydrate of tetra-n-butylammonium bromide induced by guest CO<inf>2</inf> molecules, which is found to provide high CO<inf>2</inf> storage capacity. The structure was characterized by a set of methods, including single crystal X-ray diffraction, NMR, and MD simulations.

Original languageEnglish
Pages (from-to)11476-11479
Number of pages4
JournalChemical Communications
Volume50
Issue number78
DOIs
Publication statusPublished - 2014 Oct 9

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Carbon capture
Hydrates
Bromides
Nuclear magnetic resonance
Single crystals
X ray diffraction
Molecules

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis
  • Ceramics and Composites
  • Electronic, Optical and Magnetic Materials
  • Surfaces, Coatings and Films
  • Materials Chemistry
  • Metals and Alloys

Cite this

Muromachi, S., Udachin, K. A., Shin, K., Alavi, S., Moudrakovski, I. L., Ohmura, R., & Ripmeester, J. A. (2014). Guest-induced symmetry lowering of an ionic clathrate material for carbon capture. Chemical Communications, 50(78), 11476-11479. https://doi.org/10.1039/c4cc02111h

Guest-induced symmetry lowering of an ionic clathrate material for carbon capture. / Muromachi, S.; Udachin, K. A.; Shin, K.; Alavi, S.; Moudrakovski, I. L.; Ohmura, Ryo; Ripmeester, J. A.

In: Chemical Communications, Vol. 50, No. 78, 09.10.2014, p. 11476-11479.

Research output: Contribution to journalArticle

Muromachi, S, Udachin, KA, Shin, K, Alavi, S, Moudrakovski, IL, Ohmura, R & Ripmeester, JA 2014, 'Guest-induced symmetry lowering of an ionic clathrate material for carbon capture', Chemical Communications, vol. 50, no. 78, pp. 11476-11479. https://doi.org/10.1039/c4cc02111h
Muromachi S, Udachin KA, Shin K, Alavi S, Moudrakovski IL, Ohmura R et al. Guest-induced symmetry lowering of an ionic clathrate material for carbon capture. Chemical Communications. 2014 Oct 9;50(78):11476-11479. https://doi.org/10.1039/c4cc02111h
Muromachi, S. ; Udachin, K. A. ; Shin, K. ; Alavi, S. ; Moudrakovski, I. L. ; Ohmura, Ryo ; Ripmeester, J. A. / Guest-induced symmetry lowering of an ionic clathrate material for carbon capture. In: Chemical Communications. 2014 ; Vol. 50, No. 78. pp. 11476-11479.
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