Hetero metal spin-crossover complex with LIESST iron(II) building block

Shinya Hayami, Zhonge Gu, Yasuaki Einaga, Akira Fujishima, Osamu Sato

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

LIESST iron(II) spin-crossover mononuclear complex [Fe(L)(CN)2]·H2O (1) (L is Schiff-base macrocylic ligand derived from the condensation of 2,6-diacetylpyridine with 3,6-dioxaoctane-1,8- diamine) with macro ring and two CN- bridging ligands in complex 1 can coordinate to other metal compounds, it is possible to build one-dimensional molecular-based photo-magnets. We have synthesized [Fe(L)(CN)2][Mn(hfac)2] (2) and investigated it by using magnetic susceptibility, Mossbauer spectra and IR spectra measurements. The complex 2 exhibits spin-crossover behavior (T 1/2 =110 K) on the moieties of the iron sites.

Original languageEnglish
JournalMolecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
Volume343
Publication statusPublished - 2000
Externally publishedYes

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crossovers
Iron
Metals
Ligands
iron
ligands
Diamines
Schiff Bases
metal compounds
diamines
Magnetic susceptibility
metals
imines
Magnets
Macros
Condensation
magnets
condensation
magnetic permeability
rings

ASJC Scopus subject areas

  • Condensed Matter Physics

Cite this

Hetero metal spin-crossover complex with LIESST iron(II) building block. / Hayami, Shinya; Gu, Zhonge; Einaga, Yasuaki; Fujishima, Akira; Sato, Osamu.

In: Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, Vol. 343, 2000.

Research output: Contribution to journalArticle

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AU - Sato, Osamu

PY - 2000

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