High pressure synthesis of Hg1223 superconductor under highly oxidizing atmosphere

N. Yoshida, S. Adachi, T. Tatsuki, T. Tamura, K. Tanabe, S. Fujihara, T. Kimura

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2 Citations (Scopus)

Abstract

We tried to prepare the mercury-based superconductor, HgBa2Ca2Cu3O8+δ (Hg1223), under highly oxidizing atmosphere using a high pressure technique. Samples containing Hg1223 as the main phase with TC=90-122K were obtained. CuO and a new phase were included in the samples as impurities. The a-axes of the samples were shorter than the values ever reported for Hg1223 with TC=135K. These results suggest that our Hg1223 samples had excess hole concentrations, i.e. they are over-doped. The irreversibility field (Birr) was measured for two samples with TC=118 and 94K. They had almost the same normalized temperature (1-T/TC) dependence of Birr.

Original languageEnglish
Pages (from-to)1543-1546
Number of pages4
JournalJournal of the European Ceramic Society
Volume19
Issue number6-7
DOIs
Publication statusPublished - 1999 Jun

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Keywords

  • High pressure synthesis
  • Magnetic properties
  • Oxide superconductors.
  • Superconductivity

ASJC Scopus subject areas

  • Ceramics and Composites
  • Materials Chemistry

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