Highly ruffled manganese(III) complexes of meso-tetra(tert-butyl)porphyrin

Akira Ikezaki, Mikio Nakamura

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Abstract

Extraordinarily ruffled acetato[5,10,15,20-tetra(tert-butyl)-porphinato] manganese(III) has been prepared. The 1H NMR spectra have revealed that the inversion barrier of the porphyrin ring exceeds 66 kJ mol-1 and that the spin densities are quite different between the diastereotopic β-carbon atoms.

Original languageEnglish
Pages (from-to)1046-1047
Number of pages2
JournalChemistry Letters
Volume34
Issue number7
DOIs
Publication statusPublished - 2005 Jul 5

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ASJC Scopus subject areas

  • Chemistry(all)

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