Hyperfine-resolved transition frequency list of fundamental vibration bands of H35Cl and H37Cl

Kana Iwakuni; Hideyuki Sera; Masashi Abe; Hiroyuki Sasada

doi:10.1016/j.jms.2014.09.013

Hyperfine-resolved transition frequency list of fundamental vibration bands of H³⁵Cl and H³⁷Cl

Kana Iwakuni, Hideyuki Sera, Masashi Abe, Hiroyuki Sasada

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

Sub-Doppler resolution spectroscopy of the fundamental vibration bands of H³⁵Cl and H³⁷Cl has been carried out from 87.1 to 89.9 THz. We have determined the absolute transition frequencies of the hyperfine-resolved R(0) to R(4) transitions with a typical uncertainty of 10 kHz. We have also yielded six molecular constants for each isotopomer in the vibrational excited state, which reproduce the determined frequencies with a standard deviation of about 10 kHz.

Original language	English
Pages (from-to)	19-25
Number of pages	7
Journal	Journal of Molecular Spectroscopy
Volume	306
DOIs	https://doi.org/10.1016/j.jms.2014.09.013
Publication status	Published - 2014 Dec
Externally published	Yes

Keywords

DFG
HCl
Hyperfine structure
Mid-infrared
Optical frequency comb
Sub-Doppler resolution

ASJC Scopus subject areas

Atomic and Molecular Physics, and Optics
Spectroscopy
Physical and Theoretical Chemistry

Access to Document

10.1016/j.jms.2014.09.013

Cite this

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title = "Hyperfine-resolved transition frequency list of fundamental vibration bands of H35Cl and H37Cl",

abstract = "Sub-Doppler resolution spectroscopy of the fundamental vibration bands of H35Cl and H37Cl has been carried out from 87.1 to 89.9 THz. We have determined the absolute transition frequencies of the hyperfine-resolved R(0) to R(4) transitions with a typical uncertainty of 10 kHz. We have also yielded six molecular constants for each isotopomer in the vibrational excited state, which reproduce the determined frequencies with a standard deviation of about 10 kHz.",

keywords = "DFG, HCl, Hyperfine structure, Mid-infrared, Optical frequency comb, Sub-Doppler resolution",

author = "Kana Iwakuni and Hideyuki Sera and Masashi Abe and Hiroyuki Sasada",

note = "Funding Information: This work is supported by JSPS KAKENHI Grant No. 23244084 , and the Photon Frontier Network Program of the Ministry of Education, Culture, Sports, Science and Technology, Japan . Publisher Copyright: {\textcopyright} 2014 Elsevier Inc. All rights reserved.",

year = "2014",

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doi = "10.1016/j.jms.2014.09.013",

language = "English",

volume = "306",

pages = "19--25",

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T1 - Hyperfine-resolved transition frequency list of fundamental vibration bands of H35Cl and H37Cl

AU - Iwakuni, Kana

AU - Sera, Hideyuki

AU - Abe, Masashi

AU - Sasada, Hiroyuki

N1 - Funding Information: This work is supported by JSPS KAKENHI Grant No. 23244084 , and the Photon Frontier Network Program of the Ministry of Education, Culture, Sports, Science and Technology, Japan . Publisher Copyright: © 2014 Elsevier Inc. All rights reserved.

PY - 2014/12

Y1 - 2014/12

N2 - Sub-Doppler resolution spectroscopy of the fundamental vibration bands of H35Cl and H37Cl has been carried out from 87.1 to 89.9 THz. We have determined the absolute transition frequencies of the hyperfine-resolved R(0) to R(4) transitions with a typical uncertainty of 10 kHz. We have also yielded six molecular constants for each isotopomer in the vibrational excited state, which reproduce the determined frequencies with a standard deviation of about 10 kHz.

AB - Sub-Doppler resolution spectroscopy of the fundamental vibration bands of H35Cl and H37Cl has been carried out from 87.1 to 89.9 THz. We have determined the absolute transition frequencies of the hyperfine-resolved R(0) to R(4) transitions with a typical uncertainty of 10 kHz. We have also yielded six molecular constants for each isotopomer in the vibrational excited state, which reproduce the determined frequencies with a standard deviation of about 10 kHz.

KW - DFG

KW - HCl

KW - Hyperfine structure

KW - Mid-infrared

KW - Optical frequency comb

KW - Sub-Doppler resolution

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